mF-C6H5SiMe2 anion
- Formula: C8H10FSi-
- Molecular weight: 153.2495
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C8H10FSi- + = C8H11FSi
By formula: C8H10FSi- + H+ = C8H11FSi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1577. ± 9.2 | kJ/mol | G+TS | Irie, Kikukawa, et al., 2001 | gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1544. ± 8.4 | kJ/mol | IMRE | Irie, Kikukawa, et al., 2001 | gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Irie, Kikukawa, et al., 2001
Irie, M.; Kikukawa, K.; Shimizu, N.; Mishima, M.,
Gas-phase acidities of aryldimethylsilanes,
J. Chem. Soc. Perkin Trans., 2001, 2, 6, 923-928, https://doi.org/10.1039/b100488n
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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