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CD3O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CD3O- + Methanol-D4 = C2HD7O2-

By formula: CD3O- + CD4O = C2HD7O2-

Quantity Value Units Method Reference Comment
Deltar118. ± 4.2kJ/molIMREChabinyc and Brauman, 2000gas phase; Original dG=18.8 at 350K; dS based of symmetry alone
Quantity Value Units Method Reference Comment
Deltar84.5 ± 4.2kJ/molIMREChabinyc and Brauman, 2000gas phase; Original dG=18.8 at 350K; dS based of symmetry alone

CD3O- + Deuterium cation = Methanol-D4

By formula: CD3O- + D+ = CD4O

Quantity Value Units Method Reference Comment
Deltar1597. ± 8.4kJ/molCIDCHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.
Quantity Value Units Method Reference Comment
Deltar1570. ± 8.8kJ/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CD3O- + Methanol-D4 = C2HD7O2-

By formula: CD3O- + CD4O = C2HD7O2-

Quantity Value Units Method Reference Comment
Deltar118. ± 4.2kJ/molIMREChabinyc and Brauman, 2000gas phase; Original dG=18.8 at 350K; dS based of symmetry alone
Quantity Value Units Method Reference Comment
Deltar84.5 ± 4.2kJ/molIMREChabinyc and Brauman, 2000gas phase; Original dG=18.8 at 350K; dS based of symmetry alone

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chabinyc and Brauman, 2000
Chabinyc, M.L.; Brauman, J.I., Unusual ionic hydrogen bonds: Complexes of acetylides and fluoroform, J. Am. Chem. Soc., 2000, 122, 36, 8739-8745, https://doi.org/10.1021/ja000806z . [all data]

Haas and Harrison, 1993
Haas, M.J.; Harrison, A.G., The Fragmentation of Proton-Bound Cluster Ions and the Gas-Phase Acidities of Alcohols, Int. J. Mass Spectrom. Ion Proc., 1993, 124, 2, 115, https://doi.org/10.1016/0168-1176(93)80003-W . [all data]


Notes

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