Reaction data
HO- + = (HO- • )
- Reaction by formula: HO- + H2O = (HO- • H2O)
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Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
ΔrH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
112. ± 4.2 | TDAs | Paul and Kebarle, 1990 | gas phase; B |
108.4 | Ther | Golub and Steiner, 1968 | gas phase; For a complete Fragment KE/LPES analysis, see Deyerl, Luong, et al., 2000; B |
112. ± 4.2 | TDEq | Meot-Ner and Sieck, 1986 | gas phase; B |
111. ± 4.2 | N/A | Meot-Ner (Mautner) and Speller, 1986 | gas phase; B |
100.4 | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
149. ± 29. | CIDT | De Paz, Giardini, et al., 1970 | gas phase; B |
References
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P.,
Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase,
J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076
. [all data]
Golub and Steiner, 1968
Golub, S.; Steiner, B.,
Photodetachment of {OH(H2O)}-,
J. Chem. Phys., 1968, 49, 11, 5191, https://doi.org/10.1063/1.1670021
. [all data]
Deyerl, Luong, et al., 2000
Deyerl, H.J.; Luong, A.K.; Clements, T.G.; Continetti, R.E.,
Transition state dynamics of the OH+H2O hydrogen exchange reaction studied by dissociative photodetachment of H3O2-,
Faraday Disc. Chem. Soc., 2000, 115, 147-160, https://doi.org/10.1039/a909619a
. [all data]
Meot-Ner and Sieck, 1986
Meot-Ner, M.; Sieck, L.W.,
The ionic hydrogen bond and ion solvation. 5. OH...O- bonds. Gas phase solvation and clustering of alkoxide and carboxylate anions,
J. Am. Chem. Soc., 1986, 108, 7525. [all data]
Meot-Ner (Mautner) and Speller, 1986
Meot-Ner (Mautner), M.; Speller, C.V.,
The Filling of Solvent Shells in Cluster Ions: Thermochemical Criteria nd the Effects of Isomeric Clusters,
J. Phys. Chem., 1986, 90, 25, 6616, https://doi.org/10.1021/j100283a006
. [all data]
Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P.,
Hydration of CN-, NO2-, NO3-, and HO- in the gas phase,
Can. J. Chem., 1971, 49, 3308. [all data]
De Paz, Giardini, et al., 1970
De Paz, M.; Giardini, A.G.; Friedman, L.,
Tandem-Mass Spectrometer Study of Solvated Derivatives of OD-. Total Hydration Energy of the Proton,
J. Chem. Phys., 1970, 52, 2, 687, https://doi.org/10.1063/1.1673041
. [all data]
Notes
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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