HCðCSiH2 anion


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H3Si- + Hydrogen cation = Ethyne, 1-trimethylsilyl-

By formula: C2H3Si- + H+ = C2H4Si

Quantity Value Units Method Reference Comment
Δr367.7 ± 2.3kcal/molG+TSGal, Decouzon, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr360.2 ± 2.0kcal/molIMREGal, Decouzon, et al., 2001gas phase

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]


Notes

Go To: Top, Gas phase ion energetics data, References