Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

(mesityl)2C=C(C6H4-pCF3)O anion


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C27H26F3O- + Hydrogen cation = C27H27F3O

By formula: C27H26F3O- + H+ = C27H27F3O

Quantity Value Units Method Reference Comment
Deltar1379. ± 10.kJ/molG+TSMishima, Mustanir, et al., 2000gas phase; Keto acidity; enol acidity=323.4: 323 K
Quantity Value Units Method Reference Comment
Deltar1350. ± 8.4kJ/molIMREMishima, Mustanir, et al., 2000gas phase; Keto acidity; enol acidity=323.4: 323 K

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mishima, Mustanir, et al., 2000
Mishima, M.; Mustanir; Eventova, I.; Rappoport, Z., Acidities and pK(Enol) values of stable simple enols in the gas phase, J. Chem. Soc. Perkin Trans., 2000, 2, 7, 1505-1512, https://doi.org/10.1039/b001155j . [all data]


Notes

Go To: Top, Gas phase ion energetics data, References