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pMe-C6H4S(=NSO2CF3)2NH anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C9H8F6N3O4S3- + Hydrogen cation = C9H9F6N3O4S3

By formula: C9H8F6N3O4S3- + H+ = C9H9F6N3O4S3

Quantity Value Units Method Reference Comment
Deltar1250. ± 8.4kJ/molIMRELeito, Raamat, et al., 2009gas phase
Deltar1254. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Leito, Raamat, et al., 2009
Leito, I.; Raamat, E.; Kutt, A.; Saame, J.; Kipper, K.; Koppel, I.A.; Koppel, I.; Zhang, M.; Mishima, M.; Yagupolskii, L.M.; Garlyauskayte, R.Y.; Filatov, A.A., Revision of the Gas-Phase Acidity Scale below 300 kcal mol(-1), J. Phys. Chem. A, 2009, 113, 29, 8421-8424, https://doi.org/10.1021/jp903780k . [all data]

Koppel, Koppel, et al., 2001
Koppel, I.A.; Koppel, J.; Leito, I.; Koppel, I.; Mishima, M.; Yagupolskii, L.M., The enormous acidifying effect of the supersubstituent =NSO2CF3 on the acidity of derivatives of benzenesulfonamide and toluene-p-sulfonamide in the gas phase and in dimethyl sulfoxide, J. Chem. Soc. Perkin Trans., 2001, 2, 2, 229-232, https://doi.org/10.1039/b005765g . [all data]


Notes

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