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Phosphine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(H4P+ bullet 4Phosphine) + Phosphine = (H4P+ bullet 5Phosphine)

By formula: (H4P+ bullet 4H3P) + H3P = (H4P+ bullet 5H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molDTLong and Franklin, 1974gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar55.2J/mol*KN/ALong and Franklin, 1974gas phase; Entropy change calculated or estimated

(H4P+ bullet 2Phosphine) + Phosphine = (H4P+ bullet 3Phosphine)

By formula: (H4P+ bullet 2H3P) + H3P = (H4P+ bullet 3H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet 3Phosphine) + Phosphine = (H4P+ bullet 4Phosphine)

By formula: (H4P+ bullet 3H3P) + H3P = (H4P+ bullet 4H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar27.kJ/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar62.8J/mol*KDTLong and Franklin, 1974gas phase

(H4P+ bullet Phosphine) + Phosphine = (H4P+ bullet 2Phosphine)

By formula: (H4P+ bullet H3P) + H3P = (H4P+ bullet 2H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KDTLong and Franklin, 1974gas phase

H4P+ + Phosphine = (H4P+ bullet Phosphine)

By formula: H4P+ + H3P = (H4P+ bullet H3P)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.1kJ/molDTLong and Franklin, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KDTLong and Franklin, 1974gas phase

H4P+ + Water = (H4P+ bullet Water)

By formula: H4P+ + H2O = (H4P+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Meot-Ner, 1984, Lias, Liebman, et al., 1984

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Long and Franklin, 1974
Long, J.W.; Franklin, J.L., Ion - Solvation Reactions of Phosphine, J. Am. Chem. Soc., 1974, 96, 8, 2320, https://doi.org/10.1021/ja00815a003 . [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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