Phosphoric acid, conjugate base


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

(H2O4P- • Water) + Water = (H2O4P- • 2Water)

By formula: (H2O4P- • H2O) + H2O = (H2O4P- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr12.3kcal/molES/HPMSBlades, Ho, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr20.8cal/mol*KES/HPMSBlades, Ho, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr6.1kcal/molES/HPMSBlades, Ho, et al., 1996gas phase
Δr6.1kcal/molES/HPMSBlades, Klassen, et al., 1995gas phase

H2O4P- + Water = (H2O4P- • Water)

By formula: H2O4P- + H2O = (H2O4P- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr14.0kcal/molES/HPMSBlades, Ho, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr21.0cal/mol*KES/HPMSBlades, Ho, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Δr7.7kcal/molES/HPMSBlades, Ho, et al., 1996gas phase
Δr7.6kcal/molES/HPMSBlades, Klassen, et al., 1995gas phase

(H2O4P- • 2Water) + Water = (H2O4P- • 3Water)

By formula: (H2O4P- • 2H2O) + H2O = (H2O4P- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr4.8kcal/molES/HPMSBlades, Klassen, et al., 1995gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Ho, et al., 1996
Blades, A.T.; Ho, Y.; Kebarle, P., Hydration in the Gas Phase of the Orthophosphate Anion, (HO)2PO2-, and the Conversion of the Orthophosphate to teh Metaphosphate, PO3-, Ion, J. Am. Chem. Soc., 1996, 118, 1, 196, https://doi.org/10.1021/ja952169w . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

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