Methylamine, protonated
- Formula: CH6N+
- Molecular weight: 32.0645
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 57
- Ion clustering data
- Options:
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: (CH6N+ 2H2O) + H2O = (CH6N+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 51.9 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 51.9 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: (CH6N+ H2O) + H2O = (CH6N+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 61.1 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 61.1 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 112. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 112. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31. | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: CH6N+ + H2O = (CH6N+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.3 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 78.7 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 78.7 | kJ/mol | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
![]() | 110. | J/mol*K | PHPMS | Lau and Kebarle, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.8 | kJ/mol | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields |
By formula: CH6N+ + C2H4O2 = (CH6N+ C2H4O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.0 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 89.5 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 100. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.1 | 459. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: (CH6N+ 4H2O) + H2O = (CH6N+
5H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
By formula: (CH6N+ 5H2O) + H2O = (CH6N+
6H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.4 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 259. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C5H10O2 = (CH6N+ C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 103. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
52.3 | 461. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C4H5F3O2 = (CH6N+ C4H5F3O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 89.5 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 450. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C4H10O = (CH6N+ C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 98.3 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C4H10O = (CH6N+ C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.8 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.8 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C4H8O = (CH6N+ C4H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
47.7 | 553. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C5H10O = (CH6N+ C5H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
49.4 | 549. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C2H6O = (CH6N+ C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 89.1 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
37. | 496. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C3HN = (CH6N+ C3HN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.5 | 500. | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated, CD3NH3+ |
By formula: (CH6N+ 2C2H3N) + CH4S = (CH6N+
CH4S
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
10. | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; Entropy change calculated or estimated |
By formula: (CH6N+ 2CH5N) + CH5N = (CH6N+
3CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 71.1 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 174. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
By formula: (CH6N+ CH5N) + CH5N = (CH6N+
2CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 80.3 | kJ/mol | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 167. | J/mol*K | HPMS | Holland and Castleman, 1982 | gas phase; Entropy change is questionable |
By formula: CH6N+ + C5H12O2 = (CH6N+ C5H12O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 131. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 131. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 134. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 134. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
By formula: CH6N+ + C8H18O = (CH6N+ C8H18O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 105. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 117. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
By formula: CH6N+ + C4H10O = (CH6N+ C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.0 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 92.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 105. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
CH6N+ + C12H22O = (CH6N+ C12H22O)
By formula: CH6N+ + C12H22O = (CH6N+ C12H22O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 114. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 131. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; possible misprint, ligand n(C6H13)2O |
By formula: CH6N+ + H2S = (CH6N+ H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: CH6N+ + CH5N = (CH6N+ CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 106. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 90.8 | kJ/mol | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 114. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
![]() | 98.7 | J/mol*K | PHPMS | Yamdagni and Kebarle, 1973 | gas phase |
By formula: CH6N+ + C4H7N = (CH6N+ C4H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 118. | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Speller and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated |
By formula: CH6N+ + C4H10O2 = (CH6N+ C4H10O2)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 126. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 126. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1983 | gas phase |
By formula: CH6N+ + C6H11NO3 = (CH6N+ C6H11NO3)
Bond type: Hydrogen bonds with polydentate bonding in positive ions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 168. | kJ/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 147. | J/mol*K | PHPMS | Meot-Ner, 1984, 2 | gas phase |
By formula: (CH6N+ 3H2O) + H2O = (CH6N+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: CH6N+ + C5H10O2 = (CH6N+ C5H10O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 126. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 147. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C6H14O = (CH6N+ C6H14O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 112. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C2H6O = (CH6N+ C2H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 90.0 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 123. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C8H16O2 = (CH6N+ C8H16O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 126. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 146. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C6H12O = (CH6N+ C6H12O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 113. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + CH2O2 = (CH6N+ CH2O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.5 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + CH4O = (CH6N+ CH4O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.5 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C3H6O = (CH6N+ C3H6O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C3H8O = (CH6N+ C3H8O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.0 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + CH3NO2 = (CH6N+ CH3NO2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85.8 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.2 | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + C2H3F3O = (CH6N+ C2H3F3O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.9 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + H3N = (CH6N+ H3N)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 89.5 | kJ/mol | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | PHPMS | Yamdagni and Kebarle, 1974 | gas phase |
By formula: CH6N+ + C3H6O2 = (CH6N+ C3H6O2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 98.3 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Meot-Ner, 1984 | gas phase |
By formula: CH6N+ + CH3NO = (CH6N+ CH3NO)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 126. | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase |
![]() | 126. | kJ/mol | PHPMS | Meot-Ner, 1984, 2 | gas phase |
By formula: (CH6N+ C2H3N) + CH4S = (CH6N+
CH4S
C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.7 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: (CH6N+ 2C2H3N) + C2H3N = (CH6N+
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.9 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: (CH6N+ C2H3N) + C2H3N = (CH6N+
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.8 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
By formula: CH6N+ + C7H5N = (CH6N+ C7H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 123. | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 131. | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: (CH6N+ 3CH5N) + CH5N = (CH6N+
4CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1992 | gas phase |
By formula: CH6N+ + C4H5N = (CH6N+ C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.8 | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.9 | J/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
By formula: CH6N+ + C6H10 = (CH6N+ C6H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 70.7 | J/mol*K | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase |
By formula: CH6N+ + CHN = (CH6N+ CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.0 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: CH6N+ + CH4S = (CH6N+ CH4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 56.1 | kJ/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.5 | J/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration,
J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016
. [all data]
Lau and Kebarle, 1981
Lau, Y.K.; Kebarle, P.,
Hydrogen Bonding Solvent Effect on the Basicity of Primary Amines CH3NH2, C2H5NH2, AND CF3CH2NH2,
Can. J. Chem., 1981, 59, 1, 151, https://doi.org/10.1139/v81-024
. [all data]
Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V.,
Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions,
J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543
. [all data]
Meot-Ner, 1984
Meot-Ner, (Mautner)M.,
The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects,
J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015
. [all data]
Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites,
J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020
. [all data]
Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W.,
The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters,
J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021
. [all data]
Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M.,
Intermolecular Forces in Organic Clusters,
J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024
. [all data]
Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W.,
The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes,
J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497
. [all data]
Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers,
J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012
. [all data]
Yamdagni and Kebarle, 1973
Yamdagni, R.; Kebarle, P.,
Gas - Phase Basicites of Amines. Hydrogen Bonding in Proton - Bound Amine Dimers and Proton - Induced Cyclization of alpha, omega - Diamines,
J. Am. Chem. Soc., 1973, 95, 11, 3504, https://doi.org/10.1021/ja00792a010
. [all data]
Meot-Ner, 1984, 2
Meot-Ner, (Mautner),
The Ionic Hydrogen Bond. 4. Intramolecular and Multiple Bonds. Proton Affinities, Hydration and Complexes of Amides and Amino Acid Derivatives,
J. Am. Chem. Soc., 1984, 106, 2, 278, https://doi.org/10.1021/ja00314a003
. [all data]
Yamdagni and Kebarle, 1974
Yamdagni, R.; Kebarle, P.,
The hydrogen bond energies in ClHCl- and Cl-(HCl)n,
Can. J. Chem., 1974, 52, 2449. [all data]
Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M.,
Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives,
J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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