Methylamine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Reactions 51 to 57

CH6N+ + Acetonitrile = (CH6N+ • Acetonitrile)

By formula: CH6N+ + C2H3N = (CH6N+ • C2H3N)

Quantity Value Units Method Reference Comment
Δr26.2kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Δr25.7cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Ethanethiol = (CH6N+ • Ethanethiol)

By formula: CH6N+ + C2H6S = (CH6N+ • C2H6S)

Quantity Value Units Method Reference Comment
Δr14.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Benzene = (CH6N+ • Benzene)

By formula: CH6N+ + C6H6 = (CH6N+ • C6H6)

Quantity Value Units Method Reference Comment
Δr18.8kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Δr25.1cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Methyl fluoride = (CH6N+ • Methyl fluoride)

By formula: CH6N+ + CH3F = (CH6N+ • CH3F)

Quantity Value Units Method Reference Comment
Δr11.8kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Δr23.3cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Carbon dioxide = (CH6N+ • Carbon dioxide)

By formula: CH6N+ + CO2 = (CH6N+ • CO2)

Quantity Value Units Method Reference Comment
Δr13.2kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase

CH6N+ + Methane, bromo- = (CH6N+ • Methane, bromo-)

By formula: CH6N+ + CH3Br = (CH6N+ • CH3Br)

Quantity Value Units Method Reference Comment
Δr11.2kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Δr21.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Chloromethane = (CH6N+ • Chloromethane)

By formula: CH6N+ + CH3Cl = (CH6N+ • CH3Cl)

Quantity Value Units Method Reference Comment
Δr10.7kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Δr20.6cal/mol*KPHPMSMeot-Ner, 1984gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M., Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives, J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M., Ion - Molecule Condensation Reactions: A Mechanism for Chemical Synthesis in Ionized Reducing Planetary Atmospheres, Origins Life, 1978, 9, 2, 115, https://doi.org/10.1007/BF00931409 . [all data]


Notes

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