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Methylamine, protonated


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(CH6N+ bullet 2Water) + Water = (CH6N+ bullet 3Water)

By formula: (CH6N+ bullet 2H2O) + H2O = (CH6N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar12.4kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar12.4kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar24.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.4cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.4cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar5.2kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(CH6N+ bullet Water) + Water = (CH6N+ bullet 2Water)

By formula: (CH6N+ bullet H2O) + H2O = (CH6N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar14.6kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar14.6kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.7cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.7cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar7.5kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

CH6N+ + Water = (CH6N+ bullet Water)

By formula: CH6N+ + H2O = (CH6N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar16.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar18.8kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar18.8kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.3cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.3cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar10.7kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

CH6N+ + Acetic acid = (CH6N+ bullet Acetic acid)

By formula: CH6N+ + C2H4O2 = (CH6N+ bullet C2H4O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar21.4kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar24.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.3459.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

(CH6N+ bullet 4Water) + Water = (CH6N+ bullet 5Water)

By formula: (CH6N+ bullet 4H2O) + H2O = (CH6N+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.5269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

(CH6N+ bullet 5Water) + Water = (CH6N+ bullet 6Water)

By formula: (CH6N+ bullet 5H2O) + H2O = (CH6N+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.1259.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

CH6N+ + Formic acid, butyl ester = (CH6N+ bullet Formic acid, butyl ester)

By formula: CH6N+ + C5H10O2 = (CH6N+ bullet C5H10O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.5461.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Acetic acid, trifluoro-, ethyl ester = (CH6N+ bullet Acetic acid, trifluoro-, ethyl ester)

By formula: CH6N+ + C4H5F3O2 = (CH6N+ bullet C4H5F3O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.4kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.4450.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + 1-Butanol = (CH6N+ bullet 1-Butanol)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar23.5kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.6495.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + 2-Propanol, 2-methyl- = (CH6N+ bullet 2-Propanol, 2-methyl-)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.9kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.0495.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + 2-Butanone = (CH6N+ bullet 2-Butanone)

By formula: CH6N+ + C4H8O = (CH6N+ bullet C4H8O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.2kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.4553.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + 3-Pentanone = (CH6N+ bullet 3-Pentanone)

By formula: CH6N+ + C5H10O = (CH6N+ bullet C5H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.9kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.8549.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Ethanol = (CH6N+ bullet Ethanol)

By formula: CH6N+ + C2H6O = (CH6N+ bullet C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.3kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.9496.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Propiolonitrile = (CH6N+ bullet Propiolonitrile)

By formula: CH6N+ + C3HN = (CH6N+ bullet C3HN)

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6500.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

(CH6N+ bullet 2Acetonitrile) + Methanethiol = (CH6N+ bullet Methanethiol bullet 2Acetonitrile)

By formula: (CH6N+ bullet 2C2H3N) + CH4S = (CH6N+ bullet CH4S bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.8kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.4270.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated

(CH6N+ bullet 2Methylamine) + Methylamine = (CH6N+ bullet 3Methylamine)

By formula: (CH6N+ bullet 2CH5N) + CH5N = (CH6N+ bullet 3CH5N)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar17.0kcal/molHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar41.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable

(CH6N+ bullet Methylamine) + Methylamine = (CH6N+ bullet 2Methylamine)

By formula: (CH6N+ bullet CH5N) + CH5N = (CH6N+ bullet 2CH5N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar19.2kcal/molHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar39.9cal/mol*KHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable

CH6N+ + Propane, 1,3-dimethoxy- = (CH6N+ bullet Propane, 1,3-dimethoxy-)

By formula: CH6N+ + C5H12O2 = (CH6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar31.2kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar31.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar32.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar32.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + n-Butyl ether = (CH6N+ bullet n-Butyl ether)

By formula: CH6N+ + C8H18O = (CH6N+ bullet C8H18O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar25.0kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar28.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + Ethyl ether = (CH6N+ bullet Ethyl ether)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar22.0kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar25.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + C12H22O = (CH6N+ bullet C12H22O)

By formula: CH6N+ + C12H22O = (CH6N+ bullet C12H22O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar27.2kcal/molPHPMSMeot-Ner, 1984gas phase; possible misprint, ligand n(C6H13)2O
Quantity Value Units Method Reference Comment
Deltar31.4cal/mol*KPHPMSMeot-Ner, 1984gas phase; possible misprint, ligand n(C6H13)2O

CH6N+ + Hydrogen sulfide = (CH6N+ bullet Hydrogen sulfide)

By formula: CH6N+ + H2S = (CH6N+ bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4270.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Methylamine = (CH6N+ bullet Methylamine)

By formula: CH6N+ + CH5N = (CH6N+ bullet CH5N)

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar21.7kcal/molPHPMSYamdagni and Kebarle, 1973gas phase
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar23.6cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase

CH6N+ + Butanenitrile = (CH6N+ bullet Butanenitrile)

By formula: CH6N+ + C4H7N = (CH6N+ bullet C4H7N)

Quantity Value Units Method Reference Comment
Deltar28.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

CH6N+ + Ethane, 1,2-dimethoxy- = (CH6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: CH6N+ + C4H10O2 = (CH6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar30.1kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + L-Alanine, N-acetyl-, methyl ester = (CH6N+ bullet L-Alanine, N-acetyl-, methyl ester)

By formula: CH6N+ + C6H11NO3 = (CH6N+ bullet C6H11NO3)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar40.1kcal/molPHPMSMeot-Ner, 1984, 2gas phase
Quantity Value Units Method Reference Comment
Deltar35.1cal/mol*KPHPMSMeot-Ner, 1984, 2gas phase

(CH6N+ bullet 3Water) + Water = (CH6N+ bullet 4Water)

By formula: (CH6N+ bullet 3H2O) + H2O = (CH6N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

CH6N+ + Isopropyl acetate = (CH6N+ bullet Isopropyl acetate)

By formula: CH6N+ + C5H10O2 = (CH6N+ bullet C5H10O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar35.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Di-n-propyl ether = (CH6N+ bullet Di-n-propyl ether)

By formula: CH6N+ + C6H14O = (CH6N+ bullet C6H14O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar26.7cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Dimethyl ether = (CH6N+ bullet Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ bullet C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Pentanoic acid, propyl ester = (CH6N+ bullet Pentanoic acid, propyl ester)

By formula: CH6N+ + C8H16O2 = (CH6N+ bullet C8H16O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar34.8cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + 3-Hexanone = (CH6N+ bullet 3-Hexanone)

By formula: CH6N+ + C6H12O = (CH6N+ bullet C6H12O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar27.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Formic acid = (CH6N+ bullet Formic acid)

By formula: CH6N+ + CH2O2 = (CH6N+ bullet CH2O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methyl Alcohol = (CH6N+ bullet Methyl Alcohol)

By formula: CH6N+ + CH4O = (CH6N+ bullet CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Acetone = (CH6N+ bullet Acetone)

By formula: CH6N+ + C3H6O = (CH6N+ bullet C3H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + 1-Propanol = (CH6N+ bullet 1-Propanol)

By formula: CH6N+ + C3H8O = (CH6N+ bullet C3H8O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar25.6cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methane, nitro- = (CH6N+ bullet Methane, nitro-)

By formula: CH6N+ + CH3NO2 = (CH6N+ bullet CH3NO2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar20.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Ethanol, 2,2,2-trifluoro- = (CH6N+ bullet Ethanol, 2,2,2-trifluoro-)

By formula: CH6N+ + C2H3F3O = (CH6N+ bullet C2H3F3O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.1kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar28.5cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Ammonia = (CH6N+ bullet Ammonia)

By formula: CH6N+ + H3N = (CH6N+ bullet H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar21.4kcal/molPHPMSYamdagni and Kebarle, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase

CH6N+ + Acetic acid, methyl ester = (CH6N+ bullet Acetic acid, methyl ester)

By formula: CH6N+ + C3H6O2 = (CH6N+ bullet C3H6O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar23.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Formamide = (CH6N+ bullet Formamide)

By formula: CH6N+ + CH3NO = (CH6N+ bullet CH3NO)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar30.0kcal/molPHPMSMeot-Ner, 1984, 2gas phase

(CH6N+ bullet Acetonitrile) + Methanethiol = (CH6N+ bullet Methanethiol bullet Acetonitrile)

By formula: (CH6N+ bullet C2H3N) + CH4S = (CH6N+ bullet CH4S bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.9kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(CH6N+ bullet 2Acetonitrile) + Acetonitrile = (CH6N+ bullet 3Acetonitrile)

By formula: (CH6N+ bullet 2C2H3N) + C2H3N = (CH6N+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(CH6N+ bullet Acetonitrile) + Acetonitrile = (CH6N+ bullet 2Acetonitrile)

By formula: (CH6N+ bullet C2H3N) + C2H3N = (CH6N+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar18.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Benzonitrile = (CH6N+ bullet Benzonitrile)

By formula: CH6N+ + C7H5N = (CH6N+ bullet C7H5N)

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar31.2cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

(CH6N+ bullet 3Methylamine) + Methylamine = (CH6N+ bullet 4Methylamine)

By formula: (CH6N+ bullet 3CH5N) + CH5N = (CH6N+ bullet 4CH5N)

Quantity Value Units Method Reference Comment
Deltar7.8kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar21.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

CH6N+ + Pyrrole = (CH6N+ bullet Pyrrole)

By formula: CH6N+ + C4H5N = (CH6N+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar18.6kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Cyclohexene = (CH6N+ bullet Cyclohexene)

By formula: CH6N+ + C6H10 = (CH6N+ bullet C6H10)

Quantity Value Units Method Reference Comment
Deltar11.6kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar16.9cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Hydrogen cyanide = (CH6N+ bullet Hydrogen cyanide)

By formula: CH6N+ + CHN = (CH6N+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar20.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Methanethiol = (CH6N+ bullet Methanethiol)

By formula: CH6N+ + CH4S = (CH6N+ bullet CH4S)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Hydrogen cyanide = (CH6N+ bullet Hydrogen cyanide)

By formula: CH6N+ + CHN = (CH6N+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar20.8kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Formic acid = (CH6N+ bullet Formic acid)

By formula: CH6N+ + CH2O2 = (CH6N+ bullet CH2O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methane, bromo- = (CH6N+ bullet Methane, bromo-)

By formula: CH6N+ + CH3Br = (CH6N+ bullet CH3Br)

Quantity Value Units Method Reference Comment
Deltar11.2kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Chloromethane = (CH6N+ bullet Chloromethane)

By formula: CH6N+ + CH3Cl = (CH6N+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar10.7kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar20.6cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methyl fluoride = (CH6N+ bullet Methyl fluoride)

By formula: CH6N+ + CH3F = (CH6N+ bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar11.8kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.3cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Formamide = (CH6N+ bullet Formamide)

By formula: CH6N+ + CH3NO = (CH6N+ bullet CH3NO)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar30.0kcal/molPHPMSMeot-Ner, 1984, 2gas phase

CH6N+ + Methane, nitro- = (CH6N+ bullet Methane, nitro-)

By formula: CH6N+ + CH3NO2 = (CH6N+ bullet CH3NO2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar20.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methyl Alcohol = (CH6N+ bullet Methyl Alcohol)

By formula: CH6N+ + CH4O = (CH6N+ bullet CH4O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Methanethiol = (CH6N+ bullet Methanethiol)

By formula: CH6N+ + CH4S = (CH6N+ bullet CH4S)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Methylamine = (CH6N+ bullet Methylamine)

By formula: CH6N+ + CH5N = (CH6N+ bullet CH5N)

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar21.7kcal/molPHPMSYamdagni and Kebarle, 1973gas phase
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar23.6cal/mol*KPHPMSYamdagni and Kebarle, 1973gas phase

(CH6N+ bullet Methylamine) + Methylamine = (CH6N+ bullet 2Methylamine)

By formula: (CH6N+ bullet CH5N) + CH5N = (CH6N+ bullet 2CH5N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar19.2kcal/molHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar39.9cal/mol*KHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable

(CH6N+ bullet 2Methylamine) + Methylamine = (CH6N+ bullet 3Methylamine)

By formula: (CH6N+ bullet 2CH5N) + CH5N = (CH6N+ bullet 3CH5N)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar17.0kcal/molHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar41.6cal/mol*KHPMSHolland and Castleman, 1982gas phase; Entropy change is questionable

(CH6N+ bullet 3Methylamine) + Methylamine = (CH6N+ bullet 4Methylamine)

By formula: (CH6N+ bullet 3CH5N) + CH5N = (CH6N+ bullet 4CH5N)

Quantity Value Units Method Reference Comment
Deltar7.8kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar21.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

CH6N+ + Carbon dioxide = (CH6N+ bullet Carbon dioxide)

By formula: CH6N+ + CO2 = (CH6N+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar13.2kcal/molPHPMSMeot-Ner (Mautner), 1978gas phase
Quantity Value Units Method Reference Comment
Deltar21.4cal/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase

CH6N+ + Ethanol, 2,2,2-trifluoro- = (CH6N+ bullet Ethanol, 2,2,2-trifluoro-)

By formula: CH6N+ + C2H3F3O = (CH6N+ bullet C2H3F3O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar19.1kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar28.5cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Acetonitrile = (CH6N+ bullet Acetonitrile)

By formula: CH6N+ + C2H3N = (CH6N+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar26.2kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar25.7cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

(CH6N+ bullet Acetonitrile) + Methanethiol = (CH6N+ bullet Methanethiol bullet Acetonitrile)

By formula: (CH6N+ bullet C2H3N) + CH4S = (CH6N+ bullet CH4S bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.9kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(CH6N+ bullet 2Acetonitrile) + Methanethiol = (CH6N+ bullet Methanethiol bullet 2Acetonitrile)

By formula: (CH6N+ bullet 2C2H3N) + CH4S = (CH6N+ bullet CH4S bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.8kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.4270.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated

(CH6N+ bullet Acetonitrile) + Acetonitrile = (CH6N+ bullet 2Acetonitrile)

By formula: (CH6N+ bullet C2H3N) + C2H3N = (CH6N+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar18.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(CH6N+ bullet 2Acetonitrile) + Acetonitrile = (CH6N+ bullet 3Acetonitrile)

By formula: (CH6N+ bullet 2C2H3N) + C2H3N = (CH6N+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar13.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Acetic acid = (CH6N+ bullet Acetic acid)

By formula: CH6N+ + C2H4O2 = (CH6N+ bullet C2H4O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar21.4kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar24.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.3459.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Ethanol = (CH6N+ bullet Ethanol)

By formula: CH6N+ + C2H6O = (CH6N+ bullet C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.3kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.9496.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Dimethyl ether = (CH6N+ bullet Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ bullet C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Ethanethiol = (CH6N+ bullet Ethanethiol)

By formula: CH6N+ + C2H6S = (CH6N+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Propiolonitrile = (CH6N+ bullet Propiolonitrile)

By formula: CH6N+ + C3HN = (CH6N+ bullet C3HN)

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6500.PHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated, CD3NH3+

CH6N+ + Acetone = (CH6N+ bullet Acetone)

By formula: CH6N+ + C3H6O = (CH6N+ bullet C3H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Acetic acid, methyl ester = (CH6N+ bullet Acetic acid, methyl ester)

By formula: CH6N+ + C3H6O2 = (CH6N+ bullet C3H6O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar23.5kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + 1-Propanol = (CH6N+ bullet 1-Propanol)

By formula: CH6N+ + C3H8O = (CH6N+ bullet C3H8O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar25.6cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Acetic acid, trifluoro-, ethyl ester = (CH6N+ bullet Acetic acid, trifluoro-, ethyl ester)

By formula: CH6N+ + C4H5F3O2 = (CH6N+ bullet C4H5F3O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.4kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.4450.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Pyrrole = (CH6N+ bullet Pyrrole)

By formula: CH6N+ + C4H5N = (CH6N+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar18.6kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Butanenitrile = (CH6N+ bullet Butanenitrile)

By formula: CH6N+ + C4H7N = (CH6N+ bullet C4H7N)

Quantity Value Units Method Reference Comment
Deltar28.1kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KN/ASpeller and Meot-Ner (Mautner), 1985gas phase; Entropy change calculated or estimated

CH6N+ + 2-Butanone = (CH6N+ bullet 2-Butanone)

By formula: CH6N+ + C4H8O = (CH6N+ bullet C4H8O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.2kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.4553.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Ethyl ether = (CH6N+ bullet Ethyl ether)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar22.0kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar25.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + 1-Butanol = (CH6N+ bullet 1-Butanol)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar23.5kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.6495.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + 2-Propanol, 2-methyl- = (CH6N+ bullet 2-Propanol, 2-methyl-)

By formula: CH6N+ + C4H10O = (CH6N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.9kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.0495.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Ethane, 1,2-dimethoxy- = (CH6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: CH6N+ + C4H10O2 = (CH6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar30.1kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + 3-Pentanone = (CH6N+ bullet 3-Pentanone)

By formula: CH6N+ + C5H10O = (CH6N+ bullet C5H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.9kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.8549.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Isopropyl acetate = (CH6N+ bullet Isopropyl acetate)

By formula: CH6N+ + C5H10O2 = (CH6N+ bullet C5H10O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar35.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Formic acid, butyl ester = (CH6N+ bullet Formic acid, butyl ester)

By formula: CH6N+ + C5H10O2 = (CH6N+ bullet C5H10O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AMeot-Ner, 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.5461.PHPMSMeot-Ner, 1984gas phase; Entropy change calculated or estimated

CH6N+ + Propane, 1,3-dimethoxy- = (CH6N+ bullet Propane, 1,3-dimethoxy-)

By formula: CH6N+ + C5H12O2 = (CH6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar31.2kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar31.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar32.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar32.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + Benzene = (CH6N+ bullet Benzene)

By formula: CH6N+ + C6H6 = (CH6N+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar18.8kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar25.1cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Cyclohexene = (CH6N+ bullet Cyclohexene)

By formula: CH6N+ + C6H10 = (CH6N+ bullet C6H10)

Quantity Value Units Method Reference Comment
Deltar11.6kcal/molPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar16.9cal/mol*KPHPMSDeakyne and Meot-Ner (Mautner), 1985gas phase

CH6N+ + L-Alanine, N-acetyl-, methyl ester = (CH6N+ bullet L-Alanine, N-acetyl-, methyl ester)

By formula: CH6N+ + C6H11NO3 = (CH6N+ bullet C6H11NO3)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar40.1kcal/molPHPMSMeot-Ner, 1984, 2gas phase
Quantity Value Units Method Reference Comment
Deltar35.1cal/mol*KPHPMSMeot-Ner, 1984, 2gas phase

CH6N+ + 3-Hexanone = (CH6N+ bullet 3-Hexanone)

By formula: CH6N+ + C6H12O = (CH6N+ bullet C6H12O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar27.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Di-n-propyl ether = (CH6N+ bullet Di-n-propyl ether)

By formula: CH6N+ + C6H14O = (CH6N+ bullet C6H14O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar24.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar26.7cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + Benzonitrile = (CH6N+ bullet Benzonitrile)

By formula: CH6N+ + C7H5N = (CH6N+ bullet C7H5N)

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar31.2cal/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

CH6N+ + Pentanoic acid, propyl ester = (CH6N+ bullet Pentanoic acid, propyl ester)

By formula: CH6N+ + C8H16O2 = (CH6N+ bullet C8H16O2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar30.0kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar34.8cal/mol*KPHPMSMeot-Ner, 1984gas phase

CH6N+ + n-Butyl ether = (CH6N+ bullet n-Butyl ether)

By formula: CH6N+ + C8H18O = (CH6N+ bullet C8H18O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar25.0kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar28.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

CH6N+ + C12H22O = (CH6N+ bullet C12H22O)

By formula: CH6N+ + C12H22O = (CH6N+ bullet C12H22O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar27.2kcal/molPHPMSMeot-Ner, 1984gas phase; possible misprint, ligand n(C6H13)2O
Quantity Value Units Method Reference Comment
Deltar31.4cal/mol*KPHPMSMeot-Ner, 1984gas phase; possible misprint, ligand n(C6H13)2O

CH6N+ + Water = (CH6N+ bullet Water)

By formula: CH6N+ + H2O = (CH6N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar16.8kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar18.8kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar18.8kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.3cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.3cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar10.7kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(CH6N+ bullet Water) + Water = (CH6N+ bullet 2Water)

By formula: (CH6N+ bullet H2O) + H2O = (CH6N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar14.6kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar14.6kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.7cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.7cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar7.5kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(CH6N+ bullet 2Water) + Water = (CH6N+ bullet 3Water)

By formula: (CH6N+ bullet 2H2O) + H2O = (CH6N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar12.4kcal/molPHPMSLau and Kebarle, 1981gas phase
Deltar12.4kcal/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar24.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Deltar26.4cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Deltar26.4cal/mol*KPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Deltar5.2kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields

(CH6N+ bullet 3Water) + Water = (CH6N+ bullet 4Water)

By formula: (CH6N+ bullet 3H2O) + H2O = (CH6N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

(CH6N+ bullet 4Water) + Water = (CH6N+ bullet 5Water)

By formula: (CH6N+ bullet 4H2O) + H2O = (CH6N+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.0kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.5269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

(CH6N+ bullet 5Water) + Water = (CH6N+ bullet 6Water)

By formula: (CH6N+ bullet 5H2O) + H2O = (CH6N+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.1259.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated

CH6N+ + Hydrogen sulfide = (CH6N+ bullet Hydrogen sulfide)

By formula: CH6N+ + H2S = (CH6N+ bullet H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.4270.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

CH6N+ + Ammonia = (CH6N+ bullet Ammonia)

By formula: CH6N+ + H3N = (CH6N+ bullet H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar21.4kcal/molPHPMSYamdagni and Kebarle, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Lau and Kebarle, 1981
Lau, Y.K.; Kebarle, P., Hydrogen Bonding Solvent Effect on the Basicity of Primary Amines CH3NH2, C2H5NH2, AND CF3CH2NH2, Can. J. Chem., 1981, 59, 1, 151, https://doi.org/10.1139/v81-024 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M., Intermolecular Forces in Organic Clusters, J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024 . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Yamdagni and Kebarle, 1973
Yamdagni, R.; Kebarle, P., Gas - Phase Basicites of Amines. Hydrogen Bonding in Proton - Bound Amine Dimers and Proton - Induced Cyclization of alpha, omega - Diamines, J. Am. Chem. Soc., 1973, 95, 11, 3504, https://doi.org/10.1021/ja00792a010 . [all data]

Meot-Ner, 1984, 2
Meot-Ner, (Mautner), The Ionic Hydrogen Bond. 4. Intramolecular and Multiple Bonds. Proton Affinities, Hydration and Complexes of Amides and Amino Acid Derivatives, J. Am. Chem. Soc., 1984, 106, 2, 278, https://doi.org/10.1021/ja00314a003 . [all data]

Yamdagni and Kebarle, 1974
Yamdagni, R.; Kebarle, P., The hydrogen bond energies in ClHCl- and Cl-(HCl)n, Can. J. Chem., 1974, 52, 2449. [all data]

Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M., Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives, J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034 . [all data]

Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M., Ion - Molecule Condensation Reactions: A Mechanism for Chemical Synthesis in Ionized Reducing Planetary Atmospheres, Origins Life, 1978, 9, 2, 115, https://doi.org/10.1007/BF00931409 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References