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Tripropyl amine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C9H22N+ + 1-Propanamine, N,N-dipropyl- = (C9H22N+ bullet 1-Propanamine, N,N-dipropyl-)

By formula: C9H22N+ + C9H21N = (C9H22N+ bullet C9H21N)

Quantity Value Units Method Reference Comment
Deltar98.3kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H)
Quantity Value Units Method Reference Comment
Deltar230.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.293.PHPMSMeot-Ner M. and Sieck, 1983gas phase; (H)

C9H22N+ + Water = (C9H22N+ bullet Water)

By formula: C9H22N+ + H2O = (C9H22N+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase

C9H22N+ + Hydrogen cyanide = (C9H22N+ bullet Hydrogen cyanide)

By formula: C9H22N+ + CHN = (C9H22N+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase
Quantity Value Units Method Reference Comment
Deltar121.J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner M. and Sieck, 1983
Meot-Ner M.; Sieck, L.W., The Ionic Hydrogen Bond. 1. Sterically Hindered Bonds. Solvation and Clustering of Sterically Hindered Amines and Pyridines, J. Am. Chem. Soc., 1983, 105, 10, 2956, https://doi.org/10.1021/ja00348a005 . [all data]

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]


Notes

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