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Toluene, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C7H8+ + Toluene = (C7H8+ bullet Toluene)

By formula: C7H8+ + C7H8 = (C7H8+ bullet C7H8)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar60.7kJ/molMPIErnstberger, Krause, et al., 1990gas phase
Deltar23.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer
Deltar66.9kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase

C7H8+ + Benzene = (C7H8+ bullet Benzene)

By formula: C7H8+ + C6H6 = (C7H8+ bullet C6H6)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar51.0kJ/molMPIErnstberger, Krause, et al., 1990gas phase
Deltar23.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer
Deltar51.9kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase

C7H8+ + Benzene, fluoro- = (C7H8+ bullet Benzene, fluoro-)

By formula: C7H8+ + C6H5F = (C7H8+ bullet C6H5F)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ernstberger, Krause, et al., 1990
Ernstberger, B.; Krause, H.; Kiermeier, A.; Neusser, H.J., Multiphoton ionization and dissociation of mixed van der Waals clusters in a linear reflectron time-of-flight mass spectrometer, J. Chem. Phys., 1990, 92, 9, 5285, https://doi.org/10.1063/1.458603 . [all data]

Ruhl, Bisling, et al., 1986
Ruhl, E.; Bisling, P.G.F.; Brutschy, B.; Baumgartel, H., Photoionization of Aromatic van der Waals Complexes in a Supersonic Jet, Chem. Phys. Lett., 1986, 126, 3-4, 232, https://doi.org/10.1016/S0009-2614(86)80075-6 . [all data]

Meot-Ner (Mautner), Hamlet, et al., 1978
Meot-Ner (Mautner), M.; Hamlet, P.; Hunter, E.P.; Field, F.H., Bonding Energies in Association Ions of Aromatic Molecules. Correlations with Ionization Energies, J. Am. Chem. Soc., 1978, 100, 17, 5466, https://doi.org/10.1021/ja00485a034 . [all data]


Notes

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