Toluene, positive ion


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C7H8+ + Benzene, fluoro- = (C7H8+ • Benzene, fluoro-)

By formula: C7H8+ + C6H5F = (C7H8+ • C6H5F)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr16.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer

C7H8+ + Benzene = (C7H8+ • Benzene)

By formula: C7H8+ + C6H6 = (C7H8+ • C6H6)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molMPIErnstberger, Krause, et al., 1990gas phase
Δr23.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer
Δr51.9kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase

C7H8+ + Toluene = (C7H8+ • Toluene)

By formula: C7H8+ + C7H8 = (C7H8+ • C7H8)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr60.7kJ/molMPIErnstberger, Krause, et al., 1990gas phase
Δr23.kJ/molPIRuhl, Bisling, et al., 1986gas phase; from vIP of perpendicular dimer
Δr66.9kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruhl, Bisling, et al., 1986
Ruhl, E.; Bisling, P.G.F.; Brutschy, B.; Baumgartel, H., Photoionization of Aromatic van der Waals Complexes in a Supersonic Jet, Chem. Phys. Lett., 1986, 126, 3-4, 232, https://doi.org/10.1016/S0009-2614(86)80075-6 . [all data]

Ernstberger, Krause, et al., 1990
Ernstberger, B.; Krause, H.; Kiermeier, A.; Neusser, H.J., Multiphoton ionization and dissociation of mixed van der Waals clusters in a linear reflectron time-of-flight mass spectrometer, J. Chem. Phys., 1990, 92, 9, 5285, https://doi.org/10.1063/1.458603 . [all data]

Meot-Ner (Mautner), Hamlet, et al., 1978
Meot-Ner (Mautner), M.; Hamlet, P.; Hunter, E.P.; Field, F.H., Bonding Energies in Association Ions of Aromatic Molecules. Correlations with Ionization Energies, J. Am. Chem. Soc., 1978, 100, 17, 5466, https://doi.org/10.1021/ja00485a034 . [all data]


Notes

Go To: Top, Ion clustering data, References