Methanone, dicyclopropyl-, protonated
- Formula: C7H11O+
- Molecular weight: 111.1611
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
By formula: (C7H11O+ 3H2O) + H2O = (C7H11O+
4H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.0 | J/mol*K | N/A | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 269. | PHPMS | Meot-Ner (Mautner), 1984 | gas phase; Entropy change calculated or estimated |
By formula: (C7H11O+ 2H2O) + H2O = (C7H11O+
3H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.5 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: (C7H11O+ H2O) + H2O = (C7H11O+
2H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: C7H11O+ + H2O = (C7H11O+ H2O)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 69.0 | kJ/mol | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 109. | J/mol*K | PHPMS | Meot-Ner (Mautner), 1984 | gas phase |
By formula: C7H11O+ + CHN = (C7H11O+ CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 73.6 | kJ/mol | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Speller and Meot-Ner (Mautner), 1985 | gas phase |
By formula: C7H11O+ + C2H3N = (C7H11O+ C2H3N)
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.8 | 320. | ICR | Bromilow, Abboud, et al., 1980 | gas phase; switching reaction,n((CH3)2OH+)(CH3)2O; Grimsrud and Kebarle, 1973 |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration,
J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016
. [all data]
Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M.,
The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites,
J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020
. [all data]
Bromilow, Abboud, et al., 1980
Bromilow, J.; Abboud, J.L.M.; Lebrilla, C.B.; Taft, R.W.; Scorrano, G.; Lucchini, V.,
Oxonium Ions. Solvation by Single Acetonitrile Molecules in the Gas Phase and by Bulk Solvents,
J. Am. Chem. Soc., 1980, 103, 18, 5448, https://doi.org/10.1021/ja00408a028
. [all data]
Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P.,
Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding,
J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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