Methanone, dicyclopropyl-, protonated

• Formula: C₇H₁₁O⁺
• Molecular weight: 111.1611
• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + CHN = (C₇H₁₁O⁺ • CHN)

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + C₂H₃N = (C₇H₁₁O⁺ • C₂H₃N)

Free energy of reaction

C₇H₁₁O⁺ +  = (C₇H₁₁O⁺ • )

By formula: C₇H₁₁O⁺ + H₂O = (C₇H₁₁O⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • ) +  = (C₇H₁₁O⁺ • 2)

By formula: (C₇H₁₁O⁺ • H₂O) + H₂O = (C₇H₁₁O⁺ • 2H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • 2) +  = (C₇H₁₁O⁺ • 3)

By formula: (C₇H₁₁O⁺ • 2H₂O) + H₂O = (C₇H₁₁O⁺ • 3H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(C₇H₁₁O⁺ • 3) +  = (C₇H₁₁O⁺ • 4)

By formula: (C₇H₁₁O⁺ • 3H₂O) + H₂O = (C₇H₁₁O⁺ • 4H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speller and Meot-Ner (Mautner), 1985
Speller, C.V.; Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 3. Bonds Involving Cyanides. Correlations with Proton Affinites, J. Phys. Chem., 1985, 81, 24, 5217, https://doi.org/10.1021/j100270a020 . [all data]

Bromilow, Abboud, et al., 1980
Bromilow, J.; Abboud, J.L.M.; Lebrilla, C.B.; Taft, R.W.; Scorrano, G.; Lucchini, V., Oxonium Ions. Solvation by Single Acetonitrile Molecules in the Gas Phase and by Bulk Solvents, J. Am. Chem. Soc., 1980, 103, 18, 5448, https://doi.org/10.1021/ja00408a028 . [all data]

Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Notes

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• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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