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Ethane, 1,1'-oxybis[2-methoxy-, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C6H15O3+ bullet 2Water) + Water = (C6H15O3+ bullet 3Water)

By formula: (C6H15O3+ bullet 2H2O) + H2O = (C6H15O3+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, «DELTA»rH<=, («DELTA»rS)
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, «DELTA»rH<=, («DELTA»rS)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.8257.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, «DELTA»rH<=, («DELTA»rS)

(C6H15O3+ bullet Ammonia) + Ethane, 1,1'-oxybis[2-methoxy- = (C6H15O3+ bullet Ethane, 1,1'-oxybis[2-methoxy- bullet Ammonia)

By formula: (C6H15O3+ bullet H3N) + C6H14O3 = (C6H15O3+ bullet C6H14O3 bullet H3N)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar30.5kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar50.9cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

(C6H15O3+ bullet Ethane, 1,1'-oxybis[2-methoxy-) + Water = (C6H15O3+ bullet Water bullet Ethane, 1,1'-oxybis[2-methoxy-)

By formula: (C6H15O3+ bullet C6H14O3) + H2O = (C6H15O3+ bullet H2O bullet C6H14O3)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar20.6kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar34.7cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

C6H15O3+ + Ethane, 1,1'-oxybis[2-methoxy- = (C6H15O3+ bullet Ethane, 1,1'-oxybis[2-methoxy-)

By formula: C6H15O3+ + C6H14O3 = (C6H15O3+ bullet C6H14O3)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar21.3kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar38.0cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

(C6H15O3+ bullet Water) + Water = (C6H15O3+ bullet 2Water)

By formula: (C6H15O3+ bullet H2O) + H2O = (C6H15O3+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

C6H15O3+ + Ammonia = (C6H15O3+ bullet Ammonia)

By formula: C6H15O3+ + H3N = (C6H15O3+ bullet H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar30.4kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar27.9cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase

C6H15O3+ + Water = (C6H15O3+ bullet Water)

By formula: C6H15O3+ + H2O = (C6H15O3+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar17.6kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar35.0cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1996
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S., Complexing of the Ammonium Ion by Polyethers. Comparative Complexing Thermochemistry of Ammonium, Hydronium, and Alkali Cations, J. Phys. Chem., 1996, 100, 16, 6445, https://doi.org/10.1021/jp9514943 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References