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Cyclohexanamine, protonated


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H14N+ + Ethyl ether = (C6H14N+ bullet Ethyl ether)

By formula: C6H14N+ + C4H10O = (C6H14N+ bullet C4H10O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar22.0kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar31.8cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar31.9cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + Ethane, 1,2-dimethoxy- = (C6H14N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C6H14N+ + C4H10O2 = (C6H14N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.5cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + Propane, 1,3-dimethoxy- = (C6H14N+ bullet Propane, 1,3-dimethoxy-)

By formula: C6H14N+ + C5H12O2 = (C6H14N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar28.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + L-Alanine, N-acetyl-, methyl ester = (C6H14N+ bullet L-Alanine, N-acetyl-, methyl ester)

By formula: C6H14N+ + C6H11NO3 = (C6H14N+ bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar37.8kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase
Quantity Value Units Method Reference Comment
Deltar40.9cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase

(C6H14N+ bullet L-Alanine, N-acetyl-, methyl ester) + L-Alanine, N-acetyl-, methyl ester = (C6H14N+ bullet 2L-Alanine, N-acetyl-, methyl ester)

By formula: (C6H14N+ bullet C6H11NO3) + C6H11NO3 = (C6H14N+ bullet 2C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar20.4kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase

C6H14N+ + Di-n-propyl ether = (C6H14N+ bullet Di-n-propyl ether)

By formula: C6H14N+ + C6H14O = (C6H14N+ bullet C6H14O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molPHPMSMeot-Ner, 1984gas phase
Quantity Value Units Method Reference Comment
Deltar31.2cal/mol*KPHPMSMeot-Ner, 1984gas phase

C6H14N+ + Ethane, 1,1'-oxybis[2-methoxy- = (C6H14N+ bullet Ethane, 1,1'-oxybis[2-methoxy-)

By formula: C6H14N+ + C6H14O3 = (C6H14N+ bullet C6H14O3)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar39.7kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; diglyme
Quantity Value Units Method Reference Comment
Deltar44.6cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; diglyme

C6H14N+ + 12-Crown-4 = (C6H14N+ bullet 12-Crown-4)

By formula: C6H14N+ + C8H16O4 = (C6H14N+ bullet C8H16O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar37.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar34.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + 2,5,8,11-Tetraoxadodecane = (C6H14N+ bullet 2,5,8,11-Tetraoxadodecane)

By formula: C6H14N+ + C8H18O4 = (C6H14N+ bullet C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar43.3kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Deltar43.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C6H14N+ + 15-Crown-5 = (C6H14N+ bullet 15-Crown-5)

By formula: C6H14N+ + C10H20O5 = (C6H14N+ bullet C10H20O5)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar42.3kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar36.5cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (C6H14N+ bullet 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: C6H14N+ + C12H24O6 = (C6H14N+ bullet C12H24O6)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar48. ± 4.kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar38.cal/mol*KN/AMeot-Ner (Mautner), 1983gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
23.670.PHPMSMeot-Ner (Mautner), 1983gas phase; Entropy change calculated or estimated

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]


Notes

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