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2-Methyltetrahydrofuran, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

(C5H11O+ bullet Water) + Water = (C5H11O+ bullet 2Water)

By formula: (C5H11O+ bullet H2O) + H2O = (C5H11O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

C5H11O+ + Furan, tetrahydro-2-methyl- = (C5H11O+ bullet Furan, tetrahydro-2-methyl-)

By formula: C5H11O+ + C5H10O = (C5H11O+ bullet C5H10O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar115.kJ/molPHPMSHiraoka and Takimoto, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KPHPMSHiraoka and Takimoto, 1986gas phase

C5H11O+ + Water = (C5H11O+ bullet Water)

By formula: C5H11O+ + H2O = (C5H11O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar77.4kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]

Hiraoka and Takimoto, 1986
Hiraoka, K.; Takimoto, H., Gas-Phase Stabilities of Symmetric Proton-Held Dimer Cations, J. Phys. Chem., 1986, 90, 22, 5910, https://doi.org/10.1021/j100280a090 . [all data]


Notes

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