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2-Methyltetrahydrofuran, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C5H11O+ bullet Water) + Water = (C5H11O+ bullet 2Water)

By formula: (C5H11O+ bullet H2O) + H2O = (C5H11O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

C5H11O+ + Furan, tetrahydro-2-methyl- = (C5H11O+ bullet Furan, tetrahydro-2-methyl-)

By formula: C5H11O+ + C5H10O = (C5H11O+ bullet C5H10O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar27.4kcal/molPHPMSHiraoka and Takimoto, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar26.5cal/mol*KPHPMSHiraoka and Takimoto, 1986gas phase

C5H11O+ + Water = (C5H11O+ bullet Water)

By formula: C5H11O+ + H2O = (C5H11O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar18.5kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C5H11O+ + Furan, tetrahydro-2-methyl- = (C5H11O+ bullet Furan, tetrahydro-2-methyl-)

By formula: C5H11O+ + C5H10O = (C5H11O+ bullet C5H10O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar27.4kcal/molPHPMSHiraoka and Takimoto, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar26.5cal/mol*KPHPMSHiraoka and Takimoto, 1986gas phase

C5H11O+ + Water = (C5H11O+ bullet Water)

By formula: C5H11O+ + H2O = (C5H11O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar18.5kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

(C5H11O+ bullet Water) + Water = (C5H11O+ bullet 2Water)

By formula: (C5H11O+ bullet H2O) + H2O = (C5H11O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]

Hiraoka and Takimoto, 1986
Hiraoka, K.; Takimoto, H., Gas-Phase Stabilities of Symmetric Proton-Held Dimer Cations, J. Phys. Chem., 1986, 90, 22, 5910, https://doi.org/10.1021/j100280a090 . [all data]


Notes

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