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Tetramethylhydrazine, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H12N2+ + Tetramethylhydrazine = (C4H12N2+ bullet Tetramethylhydrazine)

By formula: C4H12N2+ + C4H12N2 = (C4H12N2+ bullet C4H12N2)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar13.0kcal/molPHPMSNelsen, Rumak, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KPHPMSNelsen, Rumak, et al., 1987gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C4H12N2+ + Tetramethylhydrazine = (C4H12N2+ bullet Tetramethylhydrazine)

By formula: C4H12N2+ + C4H12N2 = (C4H12N2+ bullet C4H12N2)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar13.0kcal/molPHPMSNelsen, Rumak, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KPHPMSNelsen, Rumak, et al., 1987gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nelsen, Rumak, et al., 1987
Nelsen, S.F.; Rumak, D.T.; Meot-Ner (Mautner), M., Kinetic effects of an unusually large neutral to radical cation geometry change. Slow electron transfer rections between alkylhydrazines, J. Am. Chem. Soc., 1987, 109, 5, 1373, https://doi.org/10.1021/ja00239a015 . [all data]


Notes

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