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Disulfide, diethyl, positive ion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C4H10S+ + Diethyl sulfide = (C4H10S+ bullet Diethyl sulfide)

By formula: C4H10S+ + C4H10S = (C4H10S+ bullet C4H10S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar104.kJ/molDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 107. kJ/mol
Deltar112.kJ/molDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 120. kJ/mol
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 107. kJ/mol
Deltar143.J/mol*KDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 120. kJ/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

James, McKee, et al., 1996
James, M.A.; McKee, M.L.; Illies, A.J., Gas-phase bond strength and atomic connectivity studies of the unsymmetrical two-center three-electron ion, [Et2S...SMe2]+, J. Am. Chem. Soc., 1996, 118, 33, 7836, https://doi.org/10.1021/ja960455h . [all data]

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]


Notes

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