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Pyrrolidine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

(C4H10N+ bullet Water) + Water = (C4H10N+ bullet 2Water)

By formula: (C4H10N+ bullet H2O) + H2O = (C4H10N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.0kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar25.9cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

C4H10N+ + Water = (C4H10N+ bullet Water)

By formula: C4H10N+ + H2O = (C4H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar21.1cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

(C4H10N+ bullet Pyrrolidine) + Pyrrolidine = (C4H10N+ bullet 2Pyrrolidine)

By formula: (C4H10N+ bullet C4H9N) + C4H9N = (C4H10N+ bullet 2C4H9N)

Quantity Value Units Method Reference Comment
Deltar15.3kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

C4H10N+ + Pyrrolidine = (C4H10N+ bullet Pyrrolidine)

By formula: C4H10N+ + C4H9N = (C4H10N+ bullet C4H9N)

Quantity Value Units Method Reference Comment
Deltar22.3kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase
Quantity Value Units Method Reference Comment
Deltar23.8cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]


Notes

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