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# Trimethyl tin, positive ion

**Formula:**C_{3}H_{9}Sn^{+}**Molecular weight:**163.813**Information on this page:****Other data available:****Options:**

## Reaction thermochemistry data

**Go To:** Top, References, Notes

**
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
**

**Data compiled by:** Michael M. Meot-Ner (Mautner) and Sharon G. Lias

**Note:** Please consider using the
reaction search for this species. This page allows searching
of all reactions involving this species. A general reaction search
form is
also available. Future versions of this site may rely on
reaction search pages in place of the enumerated reaction
displays seen below.

### Individual Reactions

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{2}H_{7}N = (C_{3}H_{9}Sn^{+} C_{2}H_{7}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 44.2 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

_{r}H° | 44.1 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 30.3 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

_{r}S° | 31.8 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

28.3 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

27.4 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + H_{3}N = (C_{3}H_{9}Sn^{+} H_{3}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 36.9 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH/NH3, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 29.1 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH/NH3, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

21.6 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH/NH3, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + H_{2}O = (C_{3}H_{9}Sn^{+} H_{2}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 25.7 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 27.6 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

11.2 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{12}H_{27}N = (C_{3}H_{9}Sn^{+} C_{12}H_{27}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 48.0 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 34.3 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

30.0 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{3}H_{8}S = (C_{3}H_{9}Sn^{+} C_{3}H_{8}S)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 34.2 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.2 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

17.3 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{5}H_{10}O_{2} = (C_{3}H_{9}Sn^{+} C_{5}H_{10}O_{2})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 41.8 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33.5 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

24.2 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{9}H_{12} = (C_{3}H_{9}Sn^{+} C_{9}H_{12})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 32.0 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 31.8 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

15.3 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{5}H_{10}O_{2} = (C_{3}H_{9}Sn^{+} C_{5}H_{10}O_{2})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 40.2 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.8 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

23.0 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{6}H_{14}O = (C_{3}H_{9}Sn^{+} C_{6}H_{14}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 37.5 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33.3 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

20.0 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{8}H_{19}N = (C_{3}H_{9}Sn^{+} C_{8}H_{19}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 48.8 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33.7 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

31.1 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{6}H_{15}N = (C_{3}H_{9}Sn^{+} C_{6}H_{15}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 45.7 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33.9 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

27.9 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{6}H_{12}O_{2} = (C_{3}H_{9}Sn^{+} C_{6}H_{12}O_{2})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 41.7 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33.5 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

24.1 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{4}H_{11}N = (C_{3}H_{9}Sn^{+} C_{4}H_{11}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 46.4 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33. | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

29.1 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{4}H_{8}O_{2} = (C_{3}H_{9}Sn^{+} C_{4}H_{8}O_{2})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 40.2 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 33. | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

22.9 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{2}H_{6}O = (C_{3}H_{9}Sn^{+} C_{2}H_{6}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 34.8 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.2 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

17.9 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{4}H_{10}O = (C_{3}H_{9}Sn^{+} C_{4}H_{10}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 36.5 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.4 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

19.5 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + CH_{5}N = (C_{3}H_{9}Sn^{+} CH_{5}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 42.1 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 30.7 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

26.0 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{2}H_{3}N = (C_{3}H_{9}Sn^{+} C_{2}H_{3}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 37.5 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 31.4 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

21.0 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{4}H_{10}O = (C_{3}H_{9}Sn^{+} C_{4}H_{10}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 36.6 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.4 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

19.6 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{4}H_{8}O = (C_{3}H_{9}Sn^{+} C_{4}H_{8}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 39.3 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.8 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

22.1 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{3}H_{6}O_{2} = (C_{3}H_{9}Sn^{+} C_{3}H_{6}O_{2})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 38.4 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32.6 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

21.3 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{8}H_{10} = (C_{3}H_{9}Sn^{+} C_{8}H_{10})

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 29.9 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 31.8 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

13.2 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{5}H_{10}O = (C_{3}H_{9}Sn^{+} C_{5}H_{10}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 39.5 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 31.6 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

22.9 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{3}H_{8}O = (C_{3}H_{9}Sn^{+} C_{3}H_{8}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 35.5 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32. | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

18.7 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{3}H_{9}N = (C_{3}H_{9}Sn^{+} C_{3}H_{9}N)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 45.6 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32. | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

### Free energy of reaction

_{r}G° (kcal/mol) |
T (K) | Method | Reference | Comment |
---|---|---|---|---|

28.8 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + C_{3}H_{6}O = (C_{3}H_{9}Sn^{+} C_{3}H_{6}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 37.4 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 30.9 | cal/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

Quantity | Value | Units | Method | Reference | Comment |

_{r}G° | 21.2 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated |

C_{3}H_{9}Sn^{+} + = (C_{3}H_{9}Sn^{+} )

By formula: C_{3}H_{9}Sn^{+} + CH_{4}O = (C_{3}H_{9}Sn^{+} CH_{4}O)

Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|

_{r}H° | 32.6 | kcal/mol | PHPMS | Stone and Splinter, 1984 | gas phase |

Quantity | Value | Units | Method | Reference | Comment |

_{r}S° | 32. | cal/mol*K | PHPMS | Stone and Splinter, 1984 | gas phase |

## References

**Go To:** Top, Reaction thermochemistry data, Notes

**
Data compilation copyright
by the U.S. Secretary of Commerce on behalf of the U.S.A.
All rights reserved.
**

**Stone and Splinter, 1984**

Stone, J.A.; Splinter, D.E.,
*A high-pressure mass spectrometric study of the binding of (CH _{3})_{3}Sn^{+} to lewis bases in the gas phase*,

**Int. J. Mass Spectrom. Ion Processes**, 1984, 59, 169. [all data]

## Notes

**Go To:** Top, Reaction thermochemistry data, References

- Symbols used in this document:

T Temperature _{r}G°Free energy of reaction at standard conditions _{r}H°Enthalpy of reaction at standard conditions _{r}S°Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69:
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