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Ethane, (methylthio)-, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C3H9S+ + Ethane, (methylthio)- = (C3H9S+ bullet Ethane, (methylthio)-)

By formula: C3H9S+ + C3H8S = (C3H9S+ bullet C3H8S)

Quantity Value Units Method Reference Comment
Deltar26.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, incosistent with other sulfur compound dimers
Quantity Value Units Method Reference Comment
Deltar27.8cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; «DELTA»rH?, incosistent with other sulfur compound dimers

C3H9S+ + Water = (C3H9S+ bullet Water)

By formula: C3H9S+ + H2O = (C3H9S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar12.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.6347.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]


Notes

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