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Isopropyl, positive ion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H7+ + Hydrogen cyanide = (C3H7+ bullet Hydrogen cyanide)

By formula: C3H7+ + CHN = (C3H7+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar166.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation
Deltar129.kJ/molPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+
Quantity Value Units Method Reference Comment
Deltar189.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation
Deltar130.J/mol*KPHPMSMeot-Ner (Mautner), 1978gas phase; forms i-C3H7NCH+

C3H7+ + Methylene chloride = (C3H7+ bullet Methylene chloride)

By formula: C3H7+ + CH2Cl2 = (C3H7+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar65.3kJ/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase

C3H7+ + Chloromethane = (C3H7+ bullet Chloromethane)

By formula: C3H7+ + CH3Cl = (C3H7+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar95.8kJ/molPHPMSSen Sharma and Kebarle, 1978gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar186.J/mol*KPHPMSSen Sharma and Kebarle, 1978gas phase; Entropy change is questionable

C3H7+ + Methane = (C3H7+ bullet Methane)

By formula: C3H7+ + CH4 = (C3H7+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar10.8kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar14.kJ/molPHPMSHiraoka and Kebarle, 1976gas phase
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar84.J/mol*KPHPMSHiraoka and Kebarle, 1976gas phase

(C3H7+ bullet Methane) + Methane = (C3H7+ bullet 2Methane)

By formula: (C3H7+ bullet CH4) + CH4 = (C3H7+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar10.3kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 2Methane) + Methane = (C3H7+ bullet 3Methane)

By formula: (C3H7+ bullet 2CH4) + CH4 = (C3H7+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar9.46kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 3Methane) + Methane = (C3H7+ bullet 4Methane)

By formula: (C3H7+ bullet 3CH4) + CH4 = (C3H7+ bullet 4CH4)

Quantity Value Units Method Reference Comment
Deltar9.20kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 4Methane) + Methane = (C3H7+ bullet 5Methane)

By formula: (C3H7+ bullet 4CH4) + CH4 = (C3H7+ bullet 5CH4)

Quantity Value Units Method Reference Comment
Deltar9.20kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 5Methane) + Methane = (C3H7+ bullet 6Methane)

By formula: (C3H7+ bullet 5CH4) + CH4 = (C3H7+ bullet 6CH4)

Quantity Value Units Method Reference Comment
Deltar9.16kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 6Methane) + Methane = (C3H7+ bullet 7Methane)

By formula: (C3H7+ bullet 6CH4) + CH4 = (C3H7+ bullet 7CH4)

Quantity Value Units Method Reference Comment
Deltar9.04kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C3H7+ bullet 7Methane) + Methane = (C3H7+ bullet 8Methane)

By formula: (C3H7+ bullet 7CH4) + CH4 = (C3H7+ bullet 8CH4)

Quantity Value Units Method Reference Comment
Deltar8.28kJ/molPHPMSHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated

C3H7+ + Propane = (C3H7+ bullet Propane)

By formula: C3H7+ + C3H8 = (C3H7+ bullet C3H8)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molPHPMSSunner, Hirao, et al., 1989gas phase
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSSunner, Hirao, et al., 1989gas phase

C3H7+ + Water = (C3H7+ bullet Water)

By formula: C3H7+ + H2O = (C3H7+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar73.6kJ/molHPMSBeggs and Field, 1971gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KHPMSBeggs and Field, 1971gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product

C3H7+ + Hydrogen sulfide = (C3H7+ bullet Hydrogen sulfide)

By formula: C3H7+ + H2S = (C3H7+ bullet H2S)

Quantity Value Units Method Reference Comment
Deltar134.kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation
Quantity Value Units Method Reference Comment
Deltar146.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; condensation

C3H7+ + Hydrogen = (C3H7+ bullet Hydrogen)

By formula: C3H7+ + H2 = (C3H7+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar10.kJ/molPHPMSHiraoka and Kebarle, 1976gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka and Kebarle, 1976gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
4.170.PHPMSHiraoka and Kebarle, 1976gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Meot-Ner (Mautner), 1978
Meot-Ner (Mautner), M., Solvation of the Proton by HCN and CH3CN. Condensation of HCN with Ions in the Gas Phase., J. Am. Chem. Soc., 1978, 100, 15, 4694, https://doi.org/10.1021/ja00483a012 . [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]

Sen Sharma and Kebarle, 1978
Sen Sharma, D.K.; Kebarle, P., Binding Energies and Stabilities of Chloronium Ions from Study of the Gas - Phase Equilibria: R1+ + ClR2 = R1ClR2+, J. Am. Chem. Soc., 1978, 100, 18, 5826, https://doi.org/10.1021/ja00486a039 . [all data]

Hiraoka, Mori, et al., 1993
Hiraoka, K.; Mori, T.; Yamabe, S., The Gas-Phase Solvation of C2H5+, s-C3H7+ and s-C4H9+ with CH4. The Isomeric Structures of C2H5+ and C2H5+.CH4, Chem. Phys. Lett., 1993, 207, 2-3, 178, https://doi.org/10.1016/0009-2614(93)87011-Q . [all data]

Hiraoka and Kebarle, 1976
Hiraoka, K.; Kebarle, P., Stabilities and Energetics of Pentacoordinated Carbonium Ions. The Isomeric C2H7+ Ions and Some Higher Analogues: C3H9+ and C4H11+, J. Am. Chem. Soc., 1976, 98, 20, 6119, https://doi.org/10.1021/ja00436a009 . [all data]

Sunner, Hirao, et al., 1989
Sunner, J.A.; Hirao, K.; Kebarle, P., Hydride - Transfer Reactions. Temperature Dependence of Rate Constants for i-C3H7+ + HC(CH3)3 = C3H8 + C(CH3)3+. Clusters of i-C3H7+ and t-C4H9+ with Propane and Isobutane, J. Phys. Chem., 1989, 93, 10, 4010, https://doi.org/10.1021/j100347a030 . [all data]

Beggs and Field, 1971
Beggs, D.P.; Field, F.H., Reversible Reactions of Gas Phase Ions. II. Propane-Water System, J. Am. Chem. Soc., 1971, 93, 7, 1576, https://doi.org/10.1021/ja00736a002 . [all data]


Notes

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