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CH2COCH3, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H5O+ + 1-Propanol = (C3H5O+ bullet 1-Propanol)

By formula: C3H5O+ + C3H8O = (C3H5O+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar90.8kJ/molICRCaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990
Quantity Value Units Method Reference Comment
Deltar54.4kJ/molICRCaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990

C3H5O+ + Acetonitrile = (C3H5O+ bullet Acetonitrile)

By formula: C3H5O+ + C2H3N = (C3H5O+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar64.0kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSMeot-ner, 1988gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
39.295.FAMackay, Rakshit, et al., 1982gas phase

(C3H5O+ bullet 2Water) + Water = (C3H5O+ bullet 3Water)

By formula: (C3H5O+ bullet 2H2O) + H2O = (C3H5O+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, 1988gas phase

(C3H5O+ bullet 3Water) + Water = (C3H5O+ bullet 4Water)

By formula: (C3H5O+ bullet 3H2O) + H2O = (C3H5O+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-ner, 1988gas phase

(C3H5O+ bullet Water) + Water = (C3H5O+ bullet 2Water)

By formula: (C3H5O+ bullet H2O) + H2O = (C3H5O+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar58.2kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-ner, 1988gas phase

C3H5O+ + Water = (C3H5O+ bullet Water)

By formula: C3H5O+ + H2O = (C3H5O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar66.1kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSMeot-ner, 1988gas phase

C3H5O+ + Acetone = (C3H5O+ bullet Acetone)

By formula: C3H5O+ + C3H6O = (C3H5O+ bullet C3H6O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
35.295.FAMackay, Rakshit, et al., 1982gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H5O+ + Acetonitrile = (C3H5O+ bullet Acetonitrile)

By formula: C3H5O+ + C2H3N = (C3H5O+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar64.0kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSMeot-ner, 1988gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
39.295.FAMackay, Rakshit, et al., 1982gas phase

C3H5O+ + Acetone = (C3H5O+ bullet Acetone)

By formula: C3H5O+ + C3H6O = (C3H5O+ bullet C3H6O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
35.295.FAMackay, Rakshit, et al., 1982gas phase

C3H5O+ + 1-Propanol = (C3H5O+ bullet 1-Propanol)

By formula: C3H5O+ + C3H8O = (C3H5O+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar90.8kJ/molICRCaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990
Quantity Value Units Method Reference Comment
Deltar54.4kJ/molICRCaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990

C3H5O+ + Water = (C3H5O+ bullet Water)

By formula: C3H5O+ + H2O = (C3H5O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar66.1kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSMeot-ner, 1988gas phase

(C3H5O+ bullet Water) + Water = (C3H5O+ bullet 2Water)

By formula: (C3H5O+ bullet H2O) + H2O = (C3H5O+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar58.2kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-ner, 1988gas phase

(C3H5O+ bullet 2Water) + Water = (C3H5O+ bullet 3Water)

By formula: (C3H5O+ bullet 2H2O) + H2O = (C3H5O+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, 1988gas phase

(C3H5O+ bullet 3Water) + Water = (C3H5O+ bullet 4Water)

By formula: (C3H5O+ bullet 3H2O) + H2O = (C3H5O+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-ner, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell, Rozeboom, et al., 1984
Caldwell, G.; Rozeboom, M.D.; Kiplinger, J.P.; Bartmess, J.E., Anion-alcohol hydrogen bond strengths in the gas phase, J. Am. Chem. Soc., 1984, 106, 4660. [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase, J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076 . [all data]

Meot-ner, 1988
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Mackay, Rakshit, et al., 1982
Mackay, G.I.; Rakshit, A.B.; Bohme, D.K., An Experimental Study of the Reactivity and Relative Basicity of the Methoxide Anion in the Gas Phase at Room Temperature, and their Perturbation by Methanol Solvent, Can. J. Chem., 1982, 60, 20, 2594, https://doi.org/10.1139/v82-373 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References