Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1-Propanamine, protonated


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H10N+ + Propylamine = (C3H10N+ bullet Propylamine)

By formula: C3H10N+ + C3H9N = (C3H10N+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar103.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

(C3H10N+ bullet Propylamine) + Propylamine = (C3H10N+ bullet 2Propylamine)

By formula: (C3H10N+ bullet C3H9N) + C3H9N = (C3H10N+ bullet 2C3H9N)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar81.6kJ/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar174.J/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet 2Propylamine) + Propylamine = (C3H10N+ bullet 3Propylamine)

By formula: (C3H10N+ bullet 2C3H9N) + C3H9N = (C3H10N+ bullet 3C3H9N)

Quantity Value Units Method Reference Comment
Deltar58.6kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar71.5kJ/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar177.J/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet 3Propylamine) + Propylamine = (C3H10N+ bullet 4Propylamine)

By formula: (C3H10N+ bullet 3C3H9N) + C3H9N = (C3H10N+ bullet 4C3H9N)

Quantity Value Units Method Reference Comment
Deltar32.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

(C3H10N+ bullet 4Propylamine) + Propylamine = (C3H10N+ bullet 5Propylamine)

By formula: (C3H10N+ bullet 4C3H9N) + C3H9N = (C3H10N+ bullet 5C3H9N)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
14.174.PHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

C3H10N+ + Water = (C3H10N+ bullet Water)

By formula: C3H10N+ + H2O = (C3H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar65.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar63.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar90.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar37.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase

(C3H10N+ bullet Water) + Water = (C3H10N+ bullet 2Water)

By formula: (C3H10N+ bullet H2O) + H2O = (C3H10N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
27.293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet 2Water) + Water = (C3H10N+ bullet 3Water)

By formula: (C3H10N+ bullet 2H2O) + H2O = (C3H10N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet 3Water) + Water = (C3H10N+ bullet 4Water)

By formula: (C3H10N+ bullet 3H2O) + H2O = (C3H10N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M., Intermolecular Forces in Organic Clusters, J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024 . [all data]

Zielinska and Wincel, 1974
Zielinska, T.J.; Wincel, H., Gas - Phase Solvation of Protonated Aliphatic Amines: Methyl, Ethyl, n - Propyl, and Iso - Propylamine, Chem. Phys. Lett., 1974, 25, 354. [all data]

Blades, Klassen, et al., 1996
Blades, A.T.; Klassen, J.S.; Kebarle, P., Determination of Ion-Solvent Equilibria in the Gas Phase. Hydration of Diprotonated Diamines and Bis(trimethylammonium) Alkanes, J. Am. Chem. Soc., 1996, 118, 49, 12437, https://doi.org/10.1021/ja962641t . [all data]

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

Go To: Top, Ion clustering data, References