Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

1-Propanamine, protonated


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H10N+ + Water = (C3H10N+ bullet Water)

By formula: C3H10N+ + H2O = (C3H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar15.6kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar15.1kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar22.8cal/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar21.5cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar8.8kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase

(C3H10N+ bullet 4Propylamine) + Propylamine = (C3H10N+ bullet 5Propylamine)

By formula: (C3H10N+ bullet 4C3H9N) + C3H9N = (C3H10N+ bullet 5C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.4174.PHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

(C3H10N+ bullet 2Propylamine) + Propylamine = (C3H10N+ bullet 3Propylamine)

By formula: (C3H10N+ bullet 2C3H9N) + C3H9N = (C3H10N+ bullet 3C3H9N)

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar17.1kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar42.3cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet Propylamine) + Propylamine = (C3H10N+ bullet 2Propylamine)

By formula: (C3H10N+ bullet C3H9N) + C3H9N = (C3H10N+ bullet 2C3H9N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar19.5kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar41.6cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet 2Water) + Water = (C3H10N+ bullet 3Water)

By formula: (C3H10N+ bullet 2H2O) + H2O = (C3H10N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.6293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet Water) + Water = (C3H10N+ bullet 2Water)

By formula: (C3H10N+ bullet H2O) + H2O = (C3H10N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.4293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet 3Water) + Water = (C3H10N+ bullet 4Water)

By formula: (C3H10N+ bullet 3H2O) + H2O = (C3H10N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.9cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

(C3H10N+ bullet 3Propylamine) + Propylamine = (C3H10N+ bullet 4Propylamine)

By formula: (C3H10N+ bullet 3C3H9N) + C3H9N = (C3H10N+ bullet 4C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.7kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

C3H10N+ + Propylamine = (C3H10N+ bullet Propylamine)

By formula: C3H10N+ + C3H9N = (C3H10N+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar27.6cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C3H10N+ + Propylamine = (C3H10N+ bullet Propylamine)

By formula: C3H10N+ + C3H9N = (C3H10N+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar24.5kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar27.6cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

(C3H10N+ bullet Propylamine) + Propylamine = (C3H10N+ bullet 2Propylamine)

By formula: (C3H10N+ bullet C3H9N) + C3H9N = (C3H10N+ bullet 2C3H9N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar19.5kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar41.6cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet 2Propylamine) + Propylamine = (C3H10N+ bullet 3Propylamine)

By formula: (C3H10N+ bullet 2C3H9N) + C3H9N = (C3H10N+ bullet 3C3H9N)

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar17.1kcal/molHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase
Deltar42.3cal/mol*KHPMSZielinska and Wincel, 1974gas phase; Entropy change is questionable

(C3H10N+ bullet 3Propylamine) + Propylamine = (C3H10N+ bullet 4Propylamine)

By formula: (C3H10N+ bullet 3C3H9N) + C3H9N = (C3H10N+ bullet 4C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.7kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase

(C3H10N+ bullet 4Propylamine) + Propylamine = (C3H10N+ bullet 5Propylamine)

By formula: (C3H10N+ bullet 4C3H9N) + C3H9N = (C3H10N+ bullet 5C3H9N)

Quantity Value Units Method Reference Comment
Deltar7.kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.4174.PHPMSMeot-Ner (Mautner), 1992gas phase; Entropy change calculated or estimated

C3H10N+ + Water = (C3H10N+ bullet Water)

By formula: C3H10N+ + H2O = (C3H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar15.6kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar15.1kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar22.8cal/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase
Deltar21.5cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar8.8kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase

(C3H10N+ bullet Water) + Water = (C3H10N+ bullet 2Water)

By formula: (C3H10N+ bullet H2O) + H2O = (C3H10N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.6kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.4293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet 2Water) + Water = (C3H10N+ bullet 3Water)

By formula: (C3H10N+ bullet 2H2O) + H2O = (C3H10N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.3kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.6293.ES/HPMSBlades, Klassen, et al., 1995gas phase

(C3H10N+ bullet 3Water) + Water = (C3H10N+ bullet 4Water)

By formula: (C3H10N+ bullet 3H2O) + H2O = (C3H10N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.9kcal/molPHPMSMeot-Ner (Mautner), 1984gas phase
Quantity Value Units Method Reference Comment
Deltar24.9cal/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1996
Blades, A.T.; Klassen, J.S.; Kebarle, P., Determination of Ion-Solvent Equilibria in the Gas Phase. Hydration of Diprotonated Diamines and Bis(trimethylammonium) Alkanes, J. Am. Chem. Soc., 1996, 118, 49, 12437, https://doi.org/10.1021/ja962641t . [all data]

Meot-Ner (Mautner), 1984
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond and Ion Solvation. 2. Hydration of Onium Ions by 1 - 7 H2O Molecules. Relations Between Monomolecular, Specific and Bulk Hydration, J. Am. Chem. Soc., 1984, 106, 5, 1265, https://doi.org/10.1021/ja00317a016 . [all data]

Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M., Intermolecular Forces in Organic Clusters, J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024 . [all data]

Zielinska and Wincel, 1974
Zielinska, T.J.; Wincel, H., Gas - Phase Solvation of Protonated Aliphatic Amines: Methyl, Ethyl, n - Propyl, and Iso - Propylamine, Chem. Phys. Lett., 1974, 25, 354. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References