Dimethyl sulfide, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H7S+ + Dimethyl sulfide = (C2H7S+ • Dimethyl sulfide)

By formula: C2H7S+ + C2H6S = (C2H7S+ • C2H6S)

Quantity Value Units Method Reference Comment
Δr26.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; ΔrH?, inconsistent with other protonated sulfur dimers
Quantity Value Units Method Reference Comment
Δr28.4cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; ΔrH?, inconsistent with other protonated sulfur dimers

C2H7S+ + Water = (C2H7S+ • Water)

By formula: C2H7S+ + H2O = (C2H7S+ • H2O)

Quantity Value Units Method Reference Comment
Δr12.kcal/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984
Δr13.1kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Δr22.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(C2H7S+ • Water) + Water = (C2H7S+ • 2Water)

By formula: (C2H7S+ • H2O) + H2O = (C2H7S+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr11.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Δr23.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H7S+ + Dimethyl sulfide = (C2H7S+ • Dimethyl sulfide)

By formula: C2H7S+ + C2H6S = (C2H7S+ • C2H6S)

Quantity Value Units Method Reference Comment
Δr26.4kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; ΔrH?, inconsistent with other protonated sulfur dimers
Quantity Value Units Method Reference Comment
Δr28.4cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; ΔrH?, inconsistent with other protonated sulfur dimers

C2H7S+ + Water = (C2H7S+ • Water)

By formula: C2H7S+ + H2O = (C2H7S+ • H2O)

Quantity Value Units Method Reference Comment
Δr12.kcal/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984
Δr13.1kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Δr22.6cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

(C2H7S+ • Water) + Water = (C2H7S+ • 2Water)

By formula: (C2H7S+ • H2O) + H2O = (C2H7S+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr11.6kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase
Quantity Value Units Method Reference Comment
Δr23.0cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner) and Sieck, 1985
Meot-Ner (Mautner), M.; Sieck, L.W., The Ionic Hydrogen Bond and Ion Solvation. 4. SH+ O and NH+ S Bonds. Correlations with Proton Affinity. Mutual Effects of Weak and Strong Ligands in Mixed Clusters, J. Phys. Chem., 1985, 89, 24, 5222, https://doi.org/10.1021/j100270a021 . [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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