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Dimethyl sulfide, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C2H6S+ + Dimethyl sulfide = (C2H6S+ bullet Dimethyl sulfide)

By formula: C2H6S+ + C2H6S = (C2H6S+ bullet C2H6S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar112.kJ/molDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 115. kJ/mol
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 115. kJ/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]


Notes

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