2,2,2-Trifluoroethylamine, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C2H5F3N+ • 2Water) + Water = (C2H5F3N+ • 3Water)

By formula: (C2H5F3N+ • 2H2O) + H2O = (C2H5F3N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr122.J/mol*KPHPMSLau and Kebarle, 1981gas phase

(C2H5F3N+ • Water) + Water = (C2H5F3N+ • 2Water)

By formula: (C2H5F3N+ • H2O) + H2O = (C2H5F3N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.4kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr125.J/mol*KPHPMSLau and Kebarle, 1981gas phase

C2H5F3N+ + Water = (C2H5F3N+ • Water)

By formula: C2H5F3N+ + H2O = (C2H5F3N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr88.3kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr126.J/mol*KPHPMSLau and Kebarle, 1981gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H5F3N+ + Water = (C2H5F3N+ • Water)

By formula: C2H5F3N+ + H2O = (C2H5F3N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr88.3kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr126.J/mol*KPHPMSLau and Kebarle, 1981gas phase

(C2H5F3N+ • Water) + Water = (C2H5F3N+ • 2Water)

By formula: (C2H5F3N+ • H2O) + H2O = (C2H5F3N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.4kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr125.J/mol*KPHPMSLau and Kebarle, 1981gas phase

(C2H5F3N+ • 2Water) + Water = (C2H5F3N+ • 3Water)

By formula: (C2H5F3N+ • 2H2O) + H2O = (C2H5F3N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4kJ/molPHPMSLau and Kebarle, 1981gas phase
Quantity Value Units Method Reference Comment
Δr122.J/mol*KPHPMSLau and Kebarle, 1981gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lau and Kebarle, 1981
Lau, Y.K.; Kebarle, P., Hydrogen Bonding Solvent Effect on the Basicity of Primary Amines CH3NH2, C2H5NH2, AND CF3CH2NH2, Can. J. Chem., 1981, 59, 1, 151, https://doi.org/10.1139/v81-024 . [all data]


Notes

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