Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Ethyl, positive ion


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H5+ + Methane = (C2H5+ bullet Methane)

By formula: C2H5+ + CH4 = (C2H5+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar5.50kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar6.6kcal/molPHPMSHiroka and Kebarle, 1975gas phase
Deltar2.4kcal/molHPMSField and Beggs, 1971gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar23.4cal/mol*KPHPMSHiroka and Kebarle, 1975gas phase
Deltar8.6cal/mol*KHPMSField and Beggs, 1971gas phase; Entropy change is questionable

(C2H5+ bullet Nitrogen) + Nitrogen = (C2H5+ bullet 2Nitrogen)

By formula: (C2H5+ bullet N2) + N2 = (C2H5+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar4.6kcal/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar10.9cal/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable

(C2H5+ bullet 9Methane) + Methane = (C2H5+ bullet 10Methane)

By formula: (C2H5+ bullet 9CH4) + CH4 = (C2H5+ bullet 10CH4)

Quantity Value Units Method Reference Comment
Deltar1.91kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated

(C2H5+ bullet 2Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 3Ethyl Chloride)

By formula: (C2H5+ bullet 2C2H5Cl) + C2H5Cl = (C2H5+ bullet 3C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar4.8kcal/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar7.7cal/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable

(C2H5+ bullet Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 2Ethyl Chloride)

By formula: (C2H5+ bullet C2H5Cl) + C2H5Cl = (C2H5+ bullet 2C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar5.2kcal/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar8.7cal/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable

C2H5+ + Methylene chloride = (C2H5+ bullet Methylene chloride)

By formula: C2H5+ + CH2Cl2 = (C2H5+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar36.0kcal/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar45.1cal/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable

(C2H5+ bullet 2Methane) + Methane = (C2H5+ bullet 3Methane)

By formula: (C2H5+ bullet 2CH4) + CH4 = (C2H5+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar2.28kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 3Methane) + Methane = (C2H5+ bullet 4Methane)

By formula: (C2H5+ bullet 3CH4) + CH4 = (C2H5+ bullet 4CH4)

Quantity Value Units Method Reference Comment
Deltar2.26kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 4Methane) + Methane = (C2H5+ bullet 5Methane)

By formula: (C2H5+ bullet 4CH4) + CH4 = (C2H5+ bullet 5CH4)

Quantity Value Units Method Reference Comment
Deltar2.22kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 5Methane) + Methane = (C2H5+ bullet 6Methane)

By formula: (C2H5+ bullet 5CH4) + CH4 = (C2H5+ bullet 6CH4)

Quantity Value Units Method Reference Comment
Deltar2.21kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 6Methane) + Methane = (C2H5+ bullet 7Methane)

By formula: (C2H5+ bullet 6CH4) + CH4 = (C2H5+ bullet 7CH4)

Quantity Value Units Method Reference Comment
Deltar2.13kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 7Methane) + Methane = (C2H5+ bullet 8Methane)

By formula: (C2H5+ bullet 7CH4) + CH4 = (C2H5+ bullet 8CH4)

Quantity Value Units Method Reference Comment
Deltar2.10kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 8Methane) + Methane = (C2H5+ bullet 9Methane)

By formula: (C2H5+ bullet 8CH4) + CH4 = (C2H5+ bullet 9CH4)

Quantity Value Units Method Reference Comment
Deltar2.08kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet Methane) + Methane = (C2H5+ bullet 2Methane)

By formula: (C2H5+ bullet CH4) + CH4 = (C2H5+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar2.37kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar16.1cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

C2H5+ + Chloromethane = (C2H5+ bullet Chloromethane)

By formula: C2H5+ + CH3Cl = (C2H5+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar30.7kcal/molPHPMSSen Sharma and Kebarle, 1978gas phase
Quantity Value Units Method Reference Comment
Deltar30.7cal/mol*KPHPMSSen Sharma and Kebarle, 1978gas phase

C2H5+ + Nitrogen = (C2H5+ bullet Nitrogen)

By formula: C2H5+ + N2 = (C2H5+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar6.9kcal/molHPMSSpeller, 1983gas phase
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KHPMSSpeller, 1983gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H5+ + Methylene chloride = (C2H5+ bullet Methylene chloride)

By formula: C2H5+ + CH2Cl2 = (C2H5+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar36.0kcal/molPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar45.1cal/mol*KPHPMSSharma, Meza de Hojer, et al., 1985gas phase; Entropy change is questionable

C2H5+ + Chloromethane = (C2H5+ bullet Chloromethane)

By formula: C2H5+ + CH3Cl = (C2H5+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar30.7kcal/molPHPMSSen Sharma and Kebarle, 1978gas phase
Quantity Value Units Method Reference Comment
Deltar30.7cal/mol*KPHPMSSen Sharma and Kebarle, 1978gas phase

C2H5+ + Methane = (C2H5+ bullet Methane)

By formula: C2H5+ + CH4 = (C2H5+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar5.50kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar6.6kcal/molPHPMSHiroka and Kebarle, 1975gas phase
Deltar2.4kcal/molHPMSField and Beggs, 1971gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase
Deltar23.4cal/mol*KPHPMSHiroka and Kebarle, 1975gas phase
Deltar8.6cal/mol*KHPMSField and Beggs, 1971gas phase; Entropy change is questionable

(C2H5+ bullet Methane) + Methane = (C2H5+ bullet 2Methane)

By formula: (C2H5+ bullet CH4) + CH4 = (C2H5+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar2.37kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar16.1cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 2Methane) + Methane = (C2H5+ bullet 3Methane)

By formula: (C2H5+ bullet 2CH4) + CH4 = (C2H5+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar2.28kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 3Methane) + Methane = (C2H5+ bullet 4Methane)

By formula: (C2H5+ bullet 3CH4) + CH4 = (C2H5+ bullet 4CH4)

Quantity Value Units Method Reference Comment
Deltar2.26kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 4Methane) + Methane = (C2H5+ bullet 5Methane)

By formula: (C2H5+ bullet 4CH4) + CH4 = (C2H5+ bullet 5CH4)

Quantity Value Units Method Reference Comment
Deltar2.22kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 5Methane) + Methane = (C2H5+ bullet 6Methane)

By formula: (C2H5+ bullet 5CH4) + CH4 = (C2H5+ bullet 6CH4)

Quantity Value Units Method Reference Comment
Deltar2.21kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 6Methane) + Methane = (C2H5+ bullet 7Methane)

By formula: (C2H5+ bullet 6CH4) + CH4 = (C2H5+ bullet 7CH4)

Quantity Value Units Method Reference Comment
Deltar2.13kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 7Methane) + Methane = (C2H5+ bullet 8Methane)

By formula: (C2H5+ bullet 7CH4) + CH4 = (C2H5+ bullet 8CH4)

Quantity Value Units Method Reference Comment
Deltar2.10kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 8Methane) + Methane = (C2H5+ bullet 9Methane)

By formula: (C2H5+ bullet 8CH4) + CH4 = (C2H5+ bullet 9CH4)

Quantity Value Units Method Reference Comment
Deltar2.08kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka, Mori, et al., 1993gas phase

(C2H5+ bullet 9Methane) + Methane = (C2H5+ bullet 10Methane)

By formula: (C2H5+ bullet 9CH4) + CH4 = (C2H5+ bullet 10CH4)

Quantity Value Units Method Reference Comment
Deltar1.91kcal/molPHPMSHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Mori, et al., 1993gas phase; Entropy change calculated or estimated

(C2H5+ bullet Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 2Ethyl Chloride)

By formula: (C2H5+ bullet C2H5Cl) + C2H5Cl = (C2H5+ bullet 2C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar5.2kcal/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar8.7cal/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable

(C2H5+ bullet 2Ethyl Chloride) + Ethyl Chloride = (C2H5+ bullet 3Ethyl Chloride)

By formula: (C2H5+ bullet 2C2H5Cl) + C2H5Cl = (C2H5+ bullet 3C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar4.8kcal/molHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar7.7cal/mol*KHPMSLuczynski and Wincel, 1974gas phase; Entropy change is questionable

C2H5+ + Nitrogen = (C2H5+ bullet Nitrogen)

By formula: C2H5+ + N2 = (C2H5+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar6.9kcal/molHPMSSpeller, 1983gas phase
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KHPMSSpeller, 1983gas phase

(C2H5+ bullet Nitrogen) + Nitrogen = (C2H5+ bullet 2Nitrogen)

By formula: (C2H5+ bullet N2) + N2 = (C2H5+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar4.6kcal/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable
Quantity Value Units Method Reference Comment
Deltar10.9cal/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mori, et al., 1993
Hiraoka, K.; Mori, T.; Yamabe, S., The Gas-Phase Solvation of C2H5+, s-C3H7+ and s-C4H9+ with CH4. The Isomeric Structures of C2H5+ and C2H5+.CH4, Chem. Phys. Lett., 1993, 207, 2-3, 178, https://doi.org/10.1016/0009-2614(93)87011-Q . [all data]

Hiroka and Kebarle, 1975
Hiroka, K.; Kebarle, P., Information on the Proton Affinity and Protolysis of Propane from Measurement of the Ion Cluster Equilibrium: C2H5+ + CH4 = C3H9+, Can. J. Phys., 1975, 53, 970. [all data]

Field and Beggs, 1971
Field, F.H.; Beggs, D.P., Reversible Reactions of Gas Phase Ions. III. Studies with Methane at 0.1-1.0 Torr and 77-300 K, J. Am. Chem. Soc., 1971, 93, 7, 1585, https://doi.org/10.1021/ja00736a003 . [all data]

Speller, 1983
Speller, C.V., Ph. D. Thesis, Universite de Paris Sud, 1983. [all data]

Luczynski and Wincel, 1974
Luczynski, Z.; Wincel, H., Ion - Molecule Reactions in Ethyl Chloride, Int. J. Mass Spectrom. Ion Phys., 1974, 14, 1, 29, https://doi.org/10.1016/0020-7381(74)80059-8 . [all data]

Sharma, Meza de Hojer, et al., 1985
Sharma, D.M.S.; Meza de Hojer, S.; Kebarle, P., Stabilities of halonium ions from a study of gas-phase equilibria R+ + XR' = (RXR')+, J. Am. Chem. Soc., 1985, 107, 13, 3757, https://doi.org/10.1021/ja00299a002 . [all data]

Sen Sharma and Kebarle, 1978
Sen Sharma, D.K.; Kebarle, P., Binding Energies and Stabilities of Chloronium Ions from Study of the Gas - Phase Equilibria: R1+ + ClR2 = R1ClR2+, J. Am. Chem. Soc., 1978, 100, 18, 5826, https://doi.org/10.1021/ja00486a039 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References