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Ferrocene, positive ion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C10H10Fe+ + Acetonitrile = (C10H10Fe+ bullet Acetonitrile)

By formula: C10H10Fe+ + C2H3N = (C10H10Fe+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar11.4kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSMeot-Ner (Mautner), 1989gas phase

(C10H10Fe+ bullet Acetonitrile) + Acetonitrile = (C10H10Fe+ bullet 2Acetonitrile)

By formula: (C10H10Fe+ bullet C2H3N) + C2H3N = (C10H10Fe+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.1kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase
Quantity Value Units Method Reference Comment
Deltar16.0cal/mol*KPHPMSMeot-Ner (Mautner), 1989gas phase

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ bullet Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.7250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

C10H10Fe+ + Benzene = (C10H10Fe+ bullet Benzene)

By formula: C10H10Fe+ + C6H6 = (C10H10Fe+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar8.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.0252.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

C10H10Fe+ + Benzenamine, N,N,4-trimethyl- = (C10H10Fe+ bullet Benzenamine, N,N,4-trimethyl-)

By formula: C10H10Fe+ + C9H13N = (C10H10Fe+ bullet C9H13N)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase
Quantity Value Units Method Reference Comment
Deltar20.6cal/mol*KPHPMSMeot-Ner (Mautner), 1989gas phase

C10H10Fe+ + Ferrocene = (C10H10Fe+ bullet Ferrocene)

By formula: C10H10Fe+ + C10H10Fe = (C10H10Fe+ bullet C10H10Fe)

Quantity Value Units Method Reference Comment
Deltar12.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.9253.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1989
Meot-Ner (Mautner), M., Ion DChemistry of Ferrocene. Thermochemistry of Ionization and Protonation and Solvent Clustering. Slow and Entropy - Driven Proton - Transfer Kinetics, J. Am. Chem. Soc., 1989, 111, 8, 2830, https://doi.org/10.1021/ja00190a014 . [all data]


Notes

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