(Me2P)2CH anion


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C5H13P2- + Hydrogen cation = Bis(dimethylphosphino)methane

By formula: C5H13P2- + H+ = C5H14P2

Quantity Value Units Method Reference Comment
Deltar370.3 ± 2.2kcal/molG+TSRomer, Gatev, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Deltar362.6 ± 2.0kcal/molIMRERomer, Gatev, et al., 1998gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Romer, Gatev, et al., 1998
Romer, B.; Gatev, G.G.; Zhong, M.; Brauman, J.I., Alpha-Stabilization by Silyl and Phosphino Substitution, J. Am. Chem. Soc., 1998, 120, 12, 2919, https://doi.org/10.1021/ja970279s . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References