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N-diazirinide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

N-diazirinide anion + Hydrogen cation = 3H-Diazirine

By formula: CH3N2- + H+ = CH2N2

Quantity Value Units Method Reference Comment
Deltar1633. ± 13.kJ/molG+TSBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene
Quantity Value Units Method Reference Comment
Deltar1598. ± 13.kJ/molIMRBBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.50 ± 0.10IMRBBroadus and Kass, 1999 

Protonation reactions

N-diazirinide anion + Hydrogen cation = 3H-Diazirine

By formula: CH3N2- + H+ = CH2N2

Quantity Value Units Method Reference Comment
Deltar1633. ± 13.kJ/molG+TSBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene
Quantity Value Units Method Reference Comment
Deltar1598. ± 13.kJ/molIMRBBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Broadus and Kass, 1999
Broadus, K.M.; Kass, S.R., Conjugate Base of a Cyclic Hydrazine: Formation and Energetics of N-Diaziridyl Anion, Int. J. Mass Spectrom., 1999, 185, 179, https://doi.org/10.1016/S1387-3806(98)14164-7 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References