gold anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas34.3 ± 2.7kcal/molAcidHotop and Lineberger, 1973 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Au- + Hydrogen cation = HAu

By formula: Au- + H+ = HAu

Quantity Value Units Method Reference Comment
Δr329.3 ± 1.9kcal/molD-EAHotop and Lineberger, 1973gas phase
Quantity Value Units Method Reference Comment
Δr324.1 ± 2.0kcal/molH-TSHotop and Lineberger, 1973gas phase

Au- + Benzene, hexafluoro- = C6AuF6-

By formula: Au- + C6F6 = C6AuF6-

Quantity Value Units Method Reference Comment
Δr24.0 ± 4.0kcal/molN/AHo and Dunbar, 1999gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

Au- + Hydrogen cation = HAu

By formula: Au- + H+ = HAu

Quantity Value Units Method Reference Comment
Δr329.3 ± 1.9kcal/molD-EAHotop and Lineberger, 1973gas phase
Quantity Value Units Method Reference Comment
Δr324.1 ± 2.0kcal/molH-TSHotop and Lineberger, 1973gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Au- + Benzene, hexafluoro- = C6AuF6-

By formula: Au- + C6F6 = C6AuF6-

Quantity Value Units Method Reference Comment
Δr24.0 ± 4.0kcal/molN/AHo and Dunbar, 1999gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hotop and Lineberger, 1973
Hotop, H.; Lineberger, W.C., Dye-laser Photodetachment Studies of Au-, Pt-, PtN-, and Ag-, J. Chem. Phys., 1973, 58, 6, 2379, https://doi.org/10.1063/1.1679515 . [all data]

Ho and Dunbar, 1999
Ho, Y.P.; Dunbar, R.C., Reactions of Au+ and Au- with benzene and fluorine-substituted benzenes, Int. J. Mass Spectrom., 1999, 183, 175-184, https://doi.org/10.1016/S1387-3806(98)14245-8 . [all data]


Notes

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