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H2O..{MeOH}..MeO anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-183.6 ± 1.2kcal/molTherMeot-Ner(Mautner), 1986 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Deltar17.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Deltar10.10 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Deltar15.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Deltar6.90 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Deltar17.8 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Deltar10.10 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Deltar15.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Deltar6.90 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]


Notes

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