H3B-N(Me)2CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H11BN- + Hydrogen cation = Trimethylamine, compd. with borane (1:1)

By formula: C3H11BN- + H+ = C3H12BN

Quantity Value Units Method Reference Comment
Δr393.1 ± 2.1kcal/molG+TSRen, Workman, et al., 1998gas phase; Acid heat est. from B-N bond strength of "35-40 kcal/mol" in Ren, Workman, et al., 1998
Quantity Value Units Method Reference Comment
Δr384.0 ± 2.0kcal/molIMRBRen, Workman, et al., 1998gas phase; Acid heat est. from B-N bond strength of "35-40 kcal/mol" in Ren, Workman, et al., 1998

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]


Notes

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