Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

cyclooctatetraenide anion


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.0910 ± 0.0080LPESKato, Lee, et al., 1997 

Protonation reactions

C8H7- + Hydrogen cation = 1,3,5,7-Cyclooctatetraene

By formula: C8H7- + H+ = C8H8

Quantity Value Units Method Reference Comment
Deltar382.7 ± 2.8kcal/molG+TSKato, Lee, et al., 1997gas phase
Quantity Value Units Method Reference Comment
Deltar374.8 ± 2.5kcal/molIMREKato, Lee, et al., 1997gas phase

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kato, Lee, et al., 1997
Kato, S.; Lee, H.S.; Gareyev, R.; Wenthold, P.G.; Lineberger, W.C.; DePuy, C.H.; Bierbaum, V.M., Experimental and Computational Studies of the Structures and Energetics of Cyclooctatetraene and Its Derivatives, J. Am. Chem. Soc., 1997, 119, 33, 7863, https://doi.org/10.1021/ja971433d . [all data]


Notes

Go To: Top, Gas phase ion energetics data, References