CO..Pt3(CO)2 radical anion
- Formula: C3O3Pt3-
- Molecular weight: 669.283
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C2O2Pt3- + = C3O3Pt3-
By formula: C2O2Pt3- + CO = C3O3Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 22. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
ΔrH° | 206. ± 14. | kJ/mol | PDis | Shi, Spasov, et al., 2001 | gas phase |
C3O3Pt3- + = C4O4Pt3-
By formula: C3O3Pt3- + CO = C4O4Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 13. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
C2O2Pt3- + = C3O3Pt3-
By formula: C2O2Pt3- + CO = C3O3Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 22. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
ΔrH° | 206. ± 14. | kJ/mol | PDis | Shi, Spasov, et al., 2001 | gas phase |
C3O3Pt3- + = C4O4Pt3-
By formula: C3O3Pt3- + CO = C4O4Pt3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 102. ± 13. | kJ/mol | N/A | Grushow and Ervin, 1997 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Grushow and Ervin, 1997
Grushow, A.; Ervin, K.M.,
Ligand and Metal Binding Energies in Platinum Carbonyl Cluster Anions: Collision Induced Dissociation of PtM- and Ptm(CO)n-,
J. Chem. Phys., 1997, 106, 23, 9580, https://doi.org/10.1063/1.474116
. [all data]
Shi, Spasov, et al., 2001
Shi, Y.; Spasov, V.A.; Ervin, K.M.,
Photodesorption of carbonyl from Pt-3(CO)(n)(-) (n=1-6),
Int. J. Mass Spectrom., 2001, 204, 1-3, 197-208, https://doi.org/10.1016/S1387-3806(00)00364-X
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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