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Benzonitrile, 3-nitro- anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C7H4N2O2- + Tetrahydrofuran = (C7H4N2O2- bullet Tetrahydrofuran)

By formula: C7H4N2O2- + C4H8O = (C7H4N2O2- bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 35°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.1308.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Dimethyl Sulfoxide = (C7H4N2O2- bullet Dimethyl Sulfoxide)

By formula: C7H4N2O2- + C2H6OS = (C7H4N2O2- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar6.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.6343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- bullet Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Acetonitrile = (C7H4N2O2- bullet Acetonitrile)

By formula: C7H4N2O2- + C2H3N = (C7H4N2O2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.1343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Silicon tetrafluoride = C7H4F4N2O2Si-

By formula: C7H4N2O2- + F4Si = C7H4F4N2O2Si-

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.60kcal/molIMREWilliamson, Knighton, et al., 2001gas phase; at 150 C; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Williamson, Knighton, et al., 2001
Williamson, D.H.; Knighton, W.B.; Grimsrud, E.P., Lewis acid-base interactions of SiF4 with molecular anions formed by electron capture reactions, Int. J. Mass Spectrom., 2001, 206, 1-2, 53-61, https://doi.org/10.1016/S1387-3806(00)00388-2 . [all data]


Notes

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