LuCl3..Cl anion
- Formula: Cl4Lu-
- Molecular weight: 316.779
- Information on this page:
- Other data available:
- Options:
Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -285.22 | kcal/mol | Ther | Pogrebnoi, Kudion, et al., 1997 | EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention |
| ΔfH°gas | -308.7 ± 2.9 | kcal/mol | Ther | Kudin, Vorob'ev, et al., 2007 | value altered from reference due to conversion from electron convention to ion convention |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: Cl4Lu- + Cl3Lu = Cl7Lu2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.5 ± 2.4 | kcal/mol | TDAs | Pogrebnoi, Kudion, et al., 1997 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 61.2 ± 7.9 | kcal/mol | TDEq | Kudin, Vorob'ev, et al., 2007 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pogrebnoi, Kudion, et al., 1997
Pogrebnoi, A.; Kudion, L.S.; Kuznetsov, A.Yu.; Butman, M.F.,
Molecular and Ionic Clusters in Saturated Vapor over Lutetium Trichloride,
Rapid Commun. Mass Spectrom., 1997, 11, 14, 1536, https://doi.org/10.1002/(SICI)1097-0231(199709)11:14<1536::AID-RCM31>3.0.CO;2-D
. [all data]
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.