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(H2O)2..F anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-221.67 ± 0.71kcal/molTherHiraoka, Mizuse, et al., 1988Stated electron affinity is the Vertical Detachment Energy
Deltafgas-219.1 ± 1.1kcal/molTherPayzant, Yamdagni, et al., 1971 
Deltafgas-219.1 ± 1.1kcal/molTherArshadi, Yamdagni, et al., 1970 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
5.79 ± 0.10LPESYang, Wang, et al., 2001Stated electron affinity is the Vertical Detachment Energy

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Yang, Wang, et al., 2001
Yang, X.; Wang, X.B.; Wang, L.S., Photodetachment of F-(H2O)(n) (n=1-4): Observation of charge- transfer states [F-(H2O)(n)(+)] and the transition state of F+H2O hydrogen abstraction reaction, J. Chem. Phys., 2001, 115, 7, 2889-2892, https://doi.org/10.1063/1.1394758 . [all data]


Notes

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