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NCCH2CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4N- + Hydrogen cation = Propanenitrile

By formula: C3H4N- + H+ = C3H5N

Quantity Value Units Method Reference Comment
Deltar1640. ± 21.kJ/molG+TSMerrill, Dahlke, et al., 1996gas phase; comparable to H2O.
Quantity Value Units Method Reference Comment
Deltar1607. ± 21.kJ/molIMRBMerrill, Dahlke, et al., 1996gas phase; comparable to H2O.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.96 ± 0.24D-EAMerrill, Dahlke, et al., 1996comparable to H2O.

Protonation reactions

C3H4N- + Hydrogen cation = Propanenitrile

By formula: C3H4N- + H+ = C3H5N

Quantity Value Units Method Reference Comment
Deltar1640. ± 21.kJ/molG+TSMerrill, Dahlke, et al., 1996gas phase; comparable to H2O.
Quantity Value Units Method Reference Comment
Deltar1607. ± 21.kJ/molIMRBMerrill, Dahlke, et al., 1996gas phase; comparable to H2O.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Merrill, Dahlke, et al., 1996
Merrill, G.N.; Dahlke, G.D.; Kass, S.R., beta-Cyanoethyl Anion: Lusus Naturae, J. Am. Chem. Soc., 1996, 118, 18, 4462, https://doi.org/10.1021/ja953796o . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References