decafluoro-4-H-1-norbornanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7HF10- + Hydrogen cation = C7H2F10

By formula: C7HF10- + H+ = C7H2F10

Quantity Value Units Method Reference Comment
Δr1439. ± 8.8kJ/molG+TSKoppel, Pihl, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr1405. ± 8.4kJ/molIMREKoppel, Pihl, et al., 1994gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C7HF10- + Hydrogen cation = C7H2F10

By formula: C7HF10- + H+ = C7H2F10

Quantity Value Units Method Reference Comment
Δr1439. ± 8.8kJ/molG+TSKoppel, Pihl, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr1405. ± 8.4kJ/molIMREKoppel, Pihl, et al., 1994gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Pihl, et al., 1994
Koppel, I.A.; Pihl, V.; Koppel, I.A.; Anvia, F.; Taft, R.W., Thermodynamic acidity of (CF3)3CH and 1H-undecafluorobicyclo[2.2.1]heptane: The concept of anionic (fluorine) hyperconjugation, J. Am. Chem. Soc., 1994, 116, 19, 8654, https://doi.org/10.1021/ja00098a027 . [all data]


Notes

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