(H2O)9..SO4 dianion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

H16O12S-2 + 9Water = H18O13S-2

By formula: H16O12S-2 + 9H2O = H18O13S-2

Quantity Value Units Method Reference Comment
Δr11.8 ± 2.0kcal/molTDAsBlades and Kebarle, 2005gas phase
Quantity Value Units Method Reference Comment
Δr6.1 ± 2.0kcal/molTDAsBlades and Kebarle, 2005gas phase
Δr6.00 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase

H18O13S-2 + 10Water = H20O14S-2

By formula: H18O13S-2 + 10H2O = H20O14S-2

Quantity Value Units Method Reference Comment
Δr10.9 ± 2.0kcal/molTDAsBlades and Kebarle, 2005gas phase
Quantity Value Units Method Reference Comment
Δr5.8 ± 2.0kcal/molTDAsBlades and Kebarle, 2005gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades and Kebarle, 2005
Blades, A.T.; Kebarle, P., Sequential hydration energies of the sulfate ion, from determinations of the equilibrium constants for the gas-phase reactions: SO4(H2O)(n)(2-) = SO4(H2O)(n-1)(2-)+H2O, J. Phys. Chem. A, 2005, 109, 37, 8293-8298, https://doi.org/10.1021/jp0540353 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

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