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(H2O)8..SO4 dianion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

H14O11S-2 + 8Water = H16O12S-2

By formula: H14O11S-2 + 8H2O = H16O12S-2

Quantity Value Units Method Reference Comment
Deltar51.9 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase
Quantity Value Units Method Reference Comment
Deltar28. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase
Deltar28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase

H16O12S-2 + 9Water = H18O13S-2

By formula: H16O12S-2 + 9H2O = H18O13S-2

Quantity Value Units Method Reference Comment
Deltar49.4 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase
Quantity Value Units Method Reference Comment
Deltar26. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase
Deltar25.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades and Kebarle, 2005
Blades, A.T.; Kebarle, P., Sequential hydration energies of the sulfate ion, from determinations of the equilibrium constants for the gas-phase reactions: SO4(H2O)(n)(2-) = SO4(H2O)(n-1)(2-)+H2O, J. Phys. Chem. A, 2005, 109, 37, 8293-8298, https://doi.org/10.1021/jp0540353 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

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