HN=SiHO anion
- Formula: H2NOSi-
- Molecular weight: 60.1080
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
H2NOSi- + = H3NOSi
By formula: H2NOSi- + H+ = H3NOSi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 359.5 ± 4.2 | kcal/mol | G+TS | Hankin, Krempp, et al., 1995 | gas phase; Between CF3CH2OH,MeSH, but poor thresholds due to competeting reactions. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 352.3 ± 4.0 | kcal/mol | IMRB | Hankin, Krempp, et al., 1995 | gas phase; Between CF3CH2OH,MeSH, but poor thresholds due to competeting reactions. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hankin, Krempp, et al., 1995
Hankin, J.A.; Krempp, M.; Damrauer, R.,
Gas-phase Chemistry of the Silaformamide Ion,
Organomet., 1995, 14, 6, 2652, https://doi.org/10.1021/om00006a011
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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