H2O..O radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-135.7kJ/molTherArnold, Xu, et al., 1995Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.607 ± 0.050LPESArnold, Xu, et al., 1995Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H2O2- + 2Water = H4O3-

By formula: H2O2- + 2H2O = H4O3-

Quantity Value Units Method Reference Comment
Δr77.0 ± 7.5kJ/molLPESClements, Luong, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Xu, et al., 1995
Arnold, D.W.; Xu, C.S.; Neumark, D.M., Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O-(H2O) and H3O2, J. Chem. Phys., 1995, 102, 15, 6088, https://doi.org/10.1063/1.469343 . [all data]

Clements, Luong, et al., 2001
Clements, T.G.; Luong, A.K.; Deyerl, H.J.; Continetti, R.E., Dissociative photodetachment studies of O-(H2O)(2), OH- (H2O)(2), and the deuterated isotopomers: Energetics and three- body dissociation dynamics, J. Chem. Phys., 2001, 114, 19, 8436-8444, https://doi.org/10.1063/1.1366332 . [all data]


Notes

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